2-Chlor-N-[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]benzolsulfonamid

Gefahreninformationscode (GHS)

• Bildanzeige (GHS)

  

• Alarmwort

  Warnung

• Gefahrenhinweise

  H410：Sehr giftig für Wasserorganismen mit langfristiger Wirkung.

• Sicherheit

  P273：Freisetzung in die Umwelt vermeiden.

  P391：Verschüttete Mengen aufnehmen.

  P501：Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Chlorsulfuron Chemische Eigenschaften,Einsatz,Produktion Methoden

• R-Sätze Betriebsanweisung:

  R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.

• S-Sätze Betriebsanweisung:

  S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
  S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
  S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
  S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

• Beschreibung

  Chlorsulfuron is one of the first sulfonylurea herbicides developed and commercialized by DuPont. Dr George Levitt and his team at DuPont first synthesized chlorsulfuron in 1976, and it was commercialized for use as a herbicide in 1981. It is currently registered by DuPont in the United States, Canada, the European Union, Russia, the Ukraine, Australia, New Zealand, South Africa, Saudi Arabia, and in several countries of South America.
  Compared with many other herbicides that are applied at levels of pounds per acre (or kilograms per acre), sulfonylureas are highly effective at use rates of less than an ounce per acre (approximately 6 g per acre for chlorsulfuron).

• Chemische Eigenschaften

  Colorless, odorless crystals

• Verwenden

  Triazine urea herbicide used to control broad-leaved weeds and some annual grass weeds.

• Verwenden

  Chlorsulfuron is used as a postemergence herbicide for the control of dicotyledonous weeds, with excellent safety for wheat and other cereals crops. While chlorsulfuron is primarily used to control weeds in cereals, it can also be used in range and pasture applications. It is currently only used to a minor extent for nonfood industrial applications and right-of-way purposes.

• Definition

  ChEBI: Chlorsulfuron is an N-sulfonylurea that is N-carbamoyl-2-chlorobenzenesulfonamide in which one of the hydrogens attached to the non-sulfonylated nitrogen has been replaced by a 4-methoxy-6-methyl-1,3,5-triazin-2-yl group. A herbicide used for the control of broadleaf weeds in wheat, barley and oats. It has a role as an agrochemical, a herbicide and an EC 2.2.1.6 (acetolactate synthase) inhibitor. It is a N-sulfonylurea, a member of monochlorobenzenes and a methoxy-1,3,5-triazine.

• Allgemeine Beschreibung

  Colorless crystals. Non corrosive. Insoluble in water. Used as an herbicide.

• Air & Water Reaktionen

  Insoluble in water. Reacts slowly with water. The reaction is promoted by acid such that the pH is less than 5.0 (1/2 life of 24-48 hrs.). Reaction is also promoted by polar organic solvents such as methanol and acetone.

• Landwirtschaftliche Anwendung

  Herbicide: A selective systemic herbicide used to control most broadleaf weeds and some annual grasses in wheat, barley, oats, duram, rye, triticale and flax. Applied to non-crop sites such as rights-of-way, fence rows and roadsides.

• Handelsname

  DPX 4189®; FINESSE®; GLEAN®; GLEAN 20DF®; LANDMARK® MP; LASHER®; RIVERDALE CORSAIR®; TELAR® DF

• mögliche Exposition

  A selective systemic sulfonylurea herbicide used to control most broadleaf weeds and some annual grasses in wheat, barley, oats, duram, rye, triticale, and flax. Applied to noncrop sites such as rights-of-way, fence rows, and roadsides.

• Environmental Fate

  Soil. Degrades in soil via hydrolysis followed by microbial degradation forming low molecular weight, inactive compounds. The estimated half-life was reported to range from 4 to 6 weeks (Hartley and Kidd, 1987; Cremlyn, 1991). Microorganisms capable of degrading chlorsulfuron are Aspergillis niger, Streptomyces griseolus and Penicillium sp. (Humburg et al., 1989). One transformation product reported in field soils is 2-chlorobenzenesulfonamide (Smith, 1988)
  The reported dissipation rate of chlorsulfuron in surface soil is 0.024/day (Walker and Brown, 1983). The persistence of chlorsulfuron decreased when soil temperature and moisture were increased (Walker and Brown, 1983; Thirunarayanan et al., 1985)
  Plant. Chlorsulfuron is metabolized by plants to hydroxylated, nonphytotoxic compounds including 2-chloro-N-(((4-methoxy-6-methyl-1,3,5-triazin-2-yl)-amino)carbonyl)benzenesulfonamide (Duke et al., 1991). Devine and Born (1985) and Peterson and
  Photolytic. The reported photolysis half-lives of chlorsulfuron in distilled water, methanol and natural creek water at λ >290 nm were 18, 92 and 18 hours, respectively. In all cases, 2-chlorobenzene sulfonamide, 2-methoxy-4-methyl-6-amino-1,3,5-triazine and trace amounts of the tentatively identified compound nitroso-2-chlorophenylsulfone formed as photoproducts (Herrmann et al., 1985).

• Stoffwechselwegen

  Chlorsulfuron is metabolized in wheat and in tolerant broadleaves via different pathways where hydroxylation occurs on the methyl group of the triazine ring and at the phenyl ring of the chlorsulfuron in respective plants. With chemical degradation of chlorsulfuron on dry minerals (Syst.), two pathways of degradation are observed, one of which is direct

• Versand/Shipping

  UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

• Toxicity evaluation

  Chlorsulfuron has a moderate to short-lived fate in the environment. It does not bioaccumulate and is not volatile. In the environment, chlorsulfuron degrades via a combination of biotic and abiotic processes. Chlorsulfuron degrades in acidic solutions and soil by cleavage of the sulfonylurea bridge, Odemethylation, and hydroxylation. Chlorsulfuron is metabolized by soil microbes to numerous minor degradation products, is mineralized to CO2, and sequestered as nonextractable residues. Photodegradation is not a significant pathway of dissipation for chlorsulfuron in the environment. Hydrolytic processes are not expected to be a major contributing factor in the environmental degradation of chlorsulfuron, and would only be significant at acidic pH.

• Inkompatibilitäten

  Slowly hydrolyzes in water, releasing ammonia and forming acetate salts. May bencompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

• Waste disposal

  It is the responsibility of chemical waste generators to determine the toxicity and physical properties and of a discarded chemical and to properly identify its classification and certification as a hazardous waste and to determine the disposal method. United States Environmental Protection Agency guidelines for the classification determination are listed in 40 CFR Parts 261.3. In addition, waste generators must consult and follow all regional, national, state, and local hazardous waste laws to ensure complete and accurate classification and disposal methods. Recycle any unused portion of the material for its approved use or return it to the manufacturer or supplier. Ultimate disposal of the chemical must consider: the material’s impact on air quality; potential migration in soil or water; effects on animal, aquatic, and plant life; and conformance with environmental and public health regulations

Chlorsulfuron Upstream-Materialien And Downstream Produkte

64902-72-3, Chlorsulfuron Verwandte Suche: