ChemicalBook CAS DataBase List 3188-13-4

3188-13-4

Name	Chloromethyl ethyl ether
CAS	3188-13-4
EINECS(EC#)	221-687-5
Molecular Formula	C3H7ClO
MDL Number	MFCD00000887
Molecular Weight	94.54
MOL File	3188-13-4.mol

Chemical Properties

Appearance	CLEAR COLORLESS TO PALE YELLOW LIQUID
Melting point	-104°C
Boiling point	82 °C(lit.)
density	1.019 g/mL at 25 °C(lit.)
refractive index	n20/D 1.404(lit.)
Fp	67 °F
storage temp.	0-6°C
solubility	Chloroform (Soluble), Ethyl Acetate (Slightly)
form	Liquid
color	Clear colorless to pale yellow
Specific Gravity	1.019
InChI	InChI=1S/C3H7ClO/c1-2-5-3-4/h2-3H2,1H3
InChIKey	FCYRSDMGOLYDHL-UHFFFAOYSA-N
SMILES	CCOCCl
CAS DataBase Reference	3188-13-4(CAS DataBase Reference)
NIST Chemistry Reference	Ethane, (chloromethoxy)-(3188-13-4)
EPA Substance Registry System	3188-13-4(EPA Substance)

Safety Data

Hazard Codes	F,Xn
Risk Statements	R11:Highly Flammable. R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R36:Irritating to the eyes. R40:Limited evidence of a carcinogenic effect. less more
Safety Statements	S16:Keep away from sources of ignition-No smoking . S36/37:Wear suitable protective clothing and gloves . S9:Keep container in a well-ventilated place . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . S29:Do not empty into drains . less more
RIDADR	UN 2354 3/PG 2
WGK Germany	3
HazardClass	6.1(a)
PackingGroup	I
HS Code	29091990
Hazardous Substances Data	3188-13-4(Hazardous Substances Data)

Raw materials And Preparation Products

Hazard Information

General Description

A colorless liquid. Slightly denser than water and insoluble in water. Flash point below 73°F. May be moderately toxic by ingestion, inhalation or skin absorption. Severely irritates skin, eyes and mucous membranes.

Reactivity Profile

CHLOROMETHYL ETHYL ETHER(3188-13-4) tends to form unstable peroxides when exposed to oxygen or air. These products can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Forms salts with strong acids and addition complexes with Lewis acids. May react violently with strong oxidizing agents. I

Air & Water Reactions

Highly flammable. Insoluble in water.

Health Hazard

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Chemical Properties

clear colorless to pale yellow liquid

Uses

Chloromethyl ethyl ether can be used to prepare:

6-Benzyl-1-(ethoxymethyl)-5-iodopyrimidine-2,4(1H,3H)-dione, a key intermediate in the preparation of MKC-442 analog.
Acylation catalyst for alcohols named 1,3-bis-[(R)-1-(2-naphthyl)ethyl]imidazoliumchloride by reacting with glyoxal-bis-[(R)-1-(2-naphthyl)ethyl]imine.

Material Safety Data Sheet(MSDS)

Spectrum Detail

Well-known Reagent Company Product Information

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