1,1,2-триметилпропилборан
- английское имя1,1,2-Trimethylpropylborane
- CAS №3688-24-2
- CBNumberCB62416856
- ФормулаC6H15B
- мольный вес97.99
- файл Mol3688-24-2.mol
химическое свойство
| растворимость | sol ether, hydrocarbon, and halocarbon solvents; THF is generally the solvent of choice; reacts rapidly with protic solvents. |
1,1,2-триметилпропилборан химические свойства, назначение, производство
Использование
Readily available monoalkylboranes are useful for the regioselective hydroboration of olefins and dienes; hexylalkylboranes and hexyldialkylboranes are useful intermediates for the synthesis of asymmetric ketones, cyclic ketones, trans-disubstituted olefins, conjugated dienes, and diols.Подготовка
1,1,2-Trimethylpropylborane is most conveniently prepared from Borane-Tetrahydrofuran and 2,3-dimethyl-2-butene in THF (eq 1).
Ссылки на синтез
Journal of the American Chemical Society, 89, p. 5285, 1967 DOI: 10.1021/ja00996a037