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Diallylamine Basic information
Diallylamine Chemical Properties
  • Melting point:-88 °C (lit.)
  • Boiling point:111-112 °C (lit.)
  • Density 0.787 g/mL at 25 °C (lit.)
  • vapor density 3.35 (vs air)
  • vapor pressure 18 mm Hg ( 20 °C)
  • refractive index n20/D 1.440(lit.)
  • Flash point:60 °F
  • storage temp. Store below +30°C.
  • solubility 86g/l
  • form Liquid
  • pkapK1:9.29(+1) (25°C,μ=0.02)
  • color Clear colorless to yellow
  • PH11.5 (9.7g/l, H2O)
  • explosive limit0.93-14.2%(V)
  • Water Solubility 8.6 g/100mL
  • Sensitive Air Sensitive
  • Merck 14,2971
  • BRN 773718
  • CAS DataBase Reference124-02-7(CAS DataBase Reference)
  • NIST Chemistry Reference2-Propen-1-amine, N-2-propenyl-(124-02-7)
  • EPA Substance Registry SystemDiallylamine (124-02-7)
Safety Information
Diallylamine Usage And Synthesis
  • Chemical PropertiesDiallylamine is a flammable liquid. Diallylamine can be detected, but it is not unpleasant at 2–9 ppm and is not intolerable at 70 ppm.
  • UsesDiallylamine is manufactured from allyl chloride and ammonia. It is used as a solvent and in organic syntheses.
  • General DescriptionA liquid with a disagreeable odor. Less dense than water. Flash point 70°F. May be toxic by inhalation and skin absorption. Irritates skin and eyes. Used to make other chemicals.
  • Air & Water ReactionsHighly flammable. Soluble in water.
  • Reactivity ProfileDiallylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
  • Health HazardMay cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
  • Fire HazardFlammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
  • Safety ProfilePoison by ingestion, skin contact, and intraperitoneal routes. Moderately toxic by inhalation. Human systemic effects by inhalation route: eye lachrymation and changes in the trachea or bronchi. A skin and severe eye irritant. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NOx. See also AMINES and ALLYL COMPOUNDS.
  • Purification MethodsKeep the amine over KOH pellets overnight, decant and distil it from a few pellets of KOH at atmospheric pressure (b 108-111o), then fractionate through a Vigreux column (p 11). [Vliet J Am Chem Soc 46 1307 1924, Org Synth Coll Vol 1 201 1941.] The hydrochloride has m 164-165o (from Me2CO/EtOH). [Butler & Angels J Am Chem Soc 79 3128 1957.]
Diallylamine Preparation Products And Raw materials
Diallylamine(124-02-7)Related Product Information
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