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4-Bromoaniline

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4-Bromoaniline Basic information
4-Bromoaniline Chemical Properties
  • Melting point:56-62 °C (lit.)
  • Boiling point:230-250 °C
  • Density 1.497
  • refractive index 1.5680 (estimate)
  • Flash point:222-224°C
  • storage temp. Store below +30°C.
  • solubility ethanol: soluble0.5g/10 mL, clear, colorless to almost colorless
  • pka3.86(at 25℃)
  • form crystalline
  • color white to light yellow
  • OdorSweetish
  • Water Solubility <0.1 g/100 mL at 23 ºC
  • Merck 14,1404
  • BRN 742031
  • Stability:Stable. Combustible. Incompatible with strong oxidizing agents, peroxides, acids, acid chlorides, acid anhydrides, chloroformates. May be air sensitive.
  • InChIKeyWDFQBORIUYODSI-UHFFFAOYSA-N
  • CAS DataBase Reference106-40-1(CAS DataBase Reference)
  • NIST Chemistry Reference4-Bromoaniline(106-40-1)
  • EPA Substance Registry Systemp-Bromoaniline (106-40-1)
Safety Information
MSDS
4-Bromoaniline Usage And Synthesis
  • Chemical Propertiesbrown crystals
  • Uses4-Bromoaniline is a brominated aniline used as a building block in the preparation or pharmaceutial and organic compounds.
  • UsesIn preparation of azo dyes; condensed with formaldehyde in preparation of dihydroquinazolines.
  • Synthesis Reference(s)The Journal of Organic Chemistry, 40, p. 1867, 1975 DOI: 10.1021/jo00900a053
    Synthetic Communications, 19, p. 3047, 1989 DOI: 10.1080/00397918908052699
  • General DescriptionBrown solid with a sweet odor.
  • Air & Water Reactions4-Bromoaniline is sensitive to prolonged exposure to air. Vapor may form highly reactive mixtures in air . Insoluble in water.
  • Reactivity ProfileVapor may form highly reactive mixtures in air.
  • Fire HazardFlash point data are not available for 4-Bromoaniline, but 4-Bromoaniline is probably combustible.
  • Purification MethodsCrystallise the aniline (with appreciable loss) from aqueous EtOH. The benzoyl derivative has m 204o (from EtOH). [Beilstein 12 IV 1497.]
4-Bromoaniline Preparation Products And Raw materials
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