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Vanadium(V) trichloride oxide Structure

Vanadium(V) trichloride oxide

Chemical Properties

Melting point −76.5 °C (−105.7 °F; 196.7 K)
Boiling point 126.7 °C (260.1 °F; 399.8 K)
Density  1.826 g mL−1
vapor pressure  13.8 mm Hg ( 20 °C)
refractive index  1.6300
Flash point Not applicable
solubility  Miscible with benzene, dichloromethane and hexane.
form  liquid
color  yellow
Specific Gravity 1.84
Water Solubility  decomposes in H2O to vanadic acid and HCl; soluble methanol, ether, acetone, acids [KIR83] [MER06]
Specific Heat Capacity Cp(gas): 0.52 J/(g·K), at 25℃
Sensitive  Moisture Sensitive
Merck  14,9927
Exposure limits NIOSH: Ceiling 0.05 mg/m3
Dielectric constant 3.6(26℃)
InChI 1S/3ClH.O.V/h3*1H;;/q;;;;+3/p-3
InChIKey JBIQAPKSNFTACH-UHFFFAOYSA-K
SMILES Cl[V](Cl)(Cl)=O
LogP 0 at 20℃
CAS DataBase Reference 7727-18-6(CAS DataBase Reference)
EPA Substance Registry System Vanadium, trichlorooxo-, (T-4)- (7727-18-6)

Safety Information

Hazard Codes  T
Risk Statements  14-25-34
Safety Statements  26-27-28-36/37/39-45
RIDADR  UN 2443
WGK Germany  3
RTECS  YW2975000
F  10-21
TSCA  TSCA listed
HazardClass  8
PackingGroup  II
Storage Class 6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications Acute Tox. 3 Oral
Skin Corr. 1B
Hazardous Substances Data 7727-18-6(Hazardous Substances Data)
Toxicity LD50 orally in rats: 0.14 g/kg (Smyth)

MSDS

Usage And Synthesis

Vanadium(V) trichloride oxide Supplier