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(S)-(+)-Benzyl glycidyl ether

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(S)-(+)-Benzyl glycidyl ether Basic information
(S)-(+)-Benzyl glycidyl ether Chemical Properties
  • Boiling point:130 °C (0.1 mmHg)
  • alpha 5.1 º (c=5 in toluene)
  • Density 1.072 g/mL at 20 °C(lit.)
  • refractive index n20/D 1.517
  • Flash point:>110°C
  • storage temp. 2-8°C
  • Specific Gravity1.077
  • optical activity[α]20/D +5.1°, c = 5 in toluene
  • BRN 5246495
  • CAS DataBase Reference16495-13-9(CAS DataBase Reference)
Safety Information
  • Hazard Codes Xi
  • Risk Statements 36/37/38
  • Safety Statements 26-36-37/39
  • WGK Germany 3
  • RTECS TX2860030
  • HS Code 29109000
  • Toxicitymic-sat 660 nmol/plate MUREAV 298,197,1993
MSDS
(S)-(+)-Benzyl glycidyl ether Usage And Synthesis
  • Chemical PropertiesColorless to light yellow liqui
  • Uses(S)-(+)-Benzyl Glycidyl Ether is used as a reactant in the synthesis of (+)-Discodermolide.
  • Safety ProfileMutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.
  • Purification MethodsThis ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]
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