m-Xylene-α,α0-diamine is a colorless liquid.Molecular weight=136.22; Specific gravity (H2O:1)=1.032 at 25℃; Boiling point = 247.2℃; Freezing/Meltingpoint =15℃; Vapor pressure = 0.03 mmHg at 25℃; Flashpoint = 117℃. Hazard Identification (based on NFPA-704M Rating System): Health 3, Flammability 0, Reactivity 0.Soluble in water.
m-Xylene-α,α0-diamine is a colorless liquid.
CLEAR SLIGHTLY YELLOW LIQUID
m-Xylylenediamine can be used:
- As a monomer for the synthesis of poly(vinylogous urethane) vitrimers.
- As a starting material for the synthesis of carbamate-protected multisubstituted bis-guanidine.
- For the synthesis of polyamides by catalytic dehydrogenation with diols.
Manufacture of polyamide fibers and resins, as
a curing agent.
Colorless liquid with an amine smell. Mp: 14.1°C; bp: 273°C . Water soluble.
1,3-Bis(aminomethyl)benzene is combustible (Flash point 139°C). Incompatible with acids, acid chlorides, acid anhydrides.
Moderately toxic by skin contact and ingestion.
Mildly toxic by inhalation. A severe skin, eye,
and gastrointestinal irritant.
Moderately toxic by
skin contact and ingestion. Mildly toxic by
inhalation. A severe skin and eye irritant.
When heated to decomposition it emits
toxic fumes of NOx. Used to make
polyamide fibers and resins and as a curing
agent.
m-Xylene-α,α0-diamine is a source of
m-xylene di-isocyanate and used as an intermediate in the
manufacture of epoxy and polyamide resins.
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least30 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, getmedical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
Color Code—White: Corrosive or Contact Hazard;Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Store separately in a corrosion-resistantlocation. Prior to working with this chemical you should betrained on its proper handling and storage. Store in tightlyclosed containers in a cool, well-ventilated area away fromoxidizers (such as perchlorates, peroxides, permanganates,chlorates, and nitrates) and strong acids (such as hydrochloride, sulfuric, and nitric). Store in tightly closed containersin a cool, well-ventilated area away from heat. Sources ofignition, such as smoking and open flames, are prohibitedwhere this chemical is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard. Metalcontainers involving the transfer of 5 gallons or more ofthis chemical should be grounded and bonded. Drums mustbe equipped with self-closing valves, pressure vacuumbungs, and flame arresters. Use only nonsparking tools andequipment, especially when opening and closing containersof this chemical.
UN 2735A mines, liquid, corrosive, n.o.s, or
Polyamines, liquid, corrosive, n.o.s., Hazard class: 8; Labels:
8-Corrosive material, Technical Name Required. UN3267
Corrosive liquid, basic, organic, n.o.s., Hazard class: 8;
Labels: 8-Corrosive material, Technical Name Required.
Combustible; vapors may form explosive
mixture with air. Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions.
Keep away from alkaline materials, strong bases,
strong acids, oxoacids, and epoxides.
The ITSL for 1,3-Bis(aminomethyl)benzene is 1 μg/m3 based on a 1 hour averaging time.
