Zn(ZnOH)4(bibta)3

配位金属	Zn
配体	5,5′-bibenzotriazolate（H2bibta）CAS:15805-13-7
比表面	BET>2000m2/g

荧光：无明显荧光；其他：通过配体交换和热活化生成的亲核Zn-OH基团类似α-碳酸酐酶活性位点；簇间氢键相互作用增强了Zn-OH/Zn-O₂COH固定机制。 在溶液中，经配体交换制备过程未出现分解，稳定性较好；在潮湿条件下，CO₂吸附性能不佳，但在环境条件下稳定，暴露于空气中较长时间后，单组分等温线测量中仍保持CO₂吸附能力；热稳定性方面，经100℃加热活化，在400℃左右开始框架分解。 用于痕量CO₂捕获，能在与空气中痕量CO₂相关的分压下实现CO₂吸附。 [1] Bioinspired Metal−Organic Framework for Trace CO₂ Capture. https://doi.org/10.1021/jacs.8b06109
[2] Dual-function biomimetic carrier based facilitated transport mixed matrix membranes with high stability for efficient CO₂/N₂ separation. https://doi.org/10.1016/j.seppur.2021.120371
[3] Using Postsynthetic X-Type Ligand Exchange to Enhance CO₂ Adsorption in Metal-Organic Frameworks with Kuratowski-Type Building Units. https://doi.org/10.1021/acs.inorgchem.1c01077
[4] Adsorption and Degradation of the G‑Type Nerve Agent Soman and Its Simulant Dimethyl 4‑Nitrophenylphosphate by Metal-Exchange-Modified MFU‑4l Metal−Organic Frameworks. https://doi.org/10.1021/acs.jpcc.2c05943