ChemicalBook Product Catalog Dyes and Pigments dye Azoic dyes 4-Chloro-2-nitroaniline

4-Chloro-2-nitroaniline

Product Name4-Chloro-2-nitroaniline
CAS89-63-4
MFC6H5ClN2O2
MW172.57
EINECS201-925-4
MOL File89-63-4.mol

Chemical Properties

Melting point	117-119 °C(lit.)
Boiling point	200°C (rough estimate)
Density	1.37
refractive index	1.6460 (estimate)
Flash point	191 °C
storage temp.	room temp
solubility	0.5g/l (anhydrous substance)
Colour Index	37040
pka	pK1: 1.10(+1) (25°C)
form	Crystalline Powder or Chunks
color	Orange
PH	7 (0.5g/l, H2O, 20℃)
Water Solubility	INSOLUBLE
BRN	512436
Stability	Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference	89-63-4(CAS DataBase Reference)
NIST Chemistry Reference	Aniline, 4-chloro-2-nitro-(89-63-4)
EPA Substance Registry System	4-Chloro-2-nitroaniline (89-63-4)

Safety Information

Hazard Codes	T+,N,T
Risk Statements	26/27/28-33-51/53
Safety Statements	28-36/37-45-61-28A
RIDADR	UN 2237 6.1/PG 3
WGK Germany	2
RTECS	BX1575000
Autoignition Temperature	964 °F
Hazard Note	Very Toxic
TSCA	Yes
HazardClass	6.1
PackingGroup	III
HS Code	29214210
Hazardous Substances Data	89-63-4(Hazardous Substances Data)

MSDS

Provider	Language
4-Chloro-2-nitroaniline	English
SigmaAldrich	English
ACROS	English
ALFA	English

Usage And Synthesis

Chemical Properties

bright orange powder

Uses

A nitro-aromatic amine with mutagenicity and carcinogenicity

Uses

4-Chloro-2-nitroaniline is used as pharmaceutical intermediate.

Uses

4-Chloro-2-nitroaniline is used almost exclusively as an intermediate in the synthesis of pigments. The greatest potential for human exposure to 4-chloro-2- nitroaniline is in production and use of pigments made from the compound.

Preparation

4-Chloro-2-nitrobenzenamine of chlorine.

Production Methods

1,4-Dichloro-2-nitrobenzene is aminated at 165 ℃ by using a process similar to that described for 2- nitroaniline.

General Description

Bright orange powder.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

4-Chloro-2-nitroaniline forms explosive products on reaction with nitric acid. Can react with oxidizing agents.

Hazard

Toxic by ingestion and inhalation.

Fire Hazard

4-Chloro-2-nitroaniline is probably combustible.

Purification Methods

Crystallise the aniline from hot H2O (m 115.8-116o), EtOH, EtOH/H2O or *C6H6, and dry it for 10hours at 60o in vacuo. It has m 115.5-116o after sublimation. [Beilstein 12 H 729, 12 I 355, 12 II 396, 12 III 1649, 12 IV 1669.]

Preparation Products And Raw materials

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