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D-(-)-Salicin

Basic information Description Safety Related Supplier
D-(-)-Salicin Basic information
D-(-)-Salicin Chemical Properties
  • Melting point:196-202 °C
  • alpha -61.5 º (c=5, water)
  • Boiling point:388.65°C (rough estimate)
  • Density 1.4340
  • refractive index -62 ° (C=3, H2O)
  • storage temp. Store at RT.
  • solubility 36g/l
  • pka12.80±0.70(Predicted)
  • form Fine Crystalline Powder
  • color White
  • Water Solubility 36 g/L (15 ºC), 250 g/L (60 ºC)
  • Merck 14,8324
  • BRN 89593
  • Stability:Stability Stable, but light sensitive. Incompatible with strong oxidizing agents.
  • InChIKeyNGFMICBWJRZIBI-MICYEWLZSA-N
  • CAS DataBase Reference138-52-3(CAS DataBase Reference)
  • NIST Chemistry ReferenceSalicin(138-52-3)
  • EPA Substance Registry System.beta.-D-Glucopyranoside, 2-(hydroxymethyl)phenyl (138-52-3)
Safety Information
  • Hazard Codes Xi
  • Risk Statements 43
  • Safety Statements 36/37-37-24/25-36
  • WGK Germany 3
  • RTECS LZ5901700
  • 3-10
  • TSCA Yes
  • HS Code 29389090
MSDS
D-(-)-Salicin Usage And Synthesis
  • DescriptionD(-)-Salicin is a traditional medicine which has been known to exhibit anti-inflammation and other therapeutic activities, it can inhibit the LPS-induced inflammation in RAW264.7 cells and mouse models.
  • Chemical Propertieswhite crystals or powder
  • Usesanalgesic, antipyretic
  • UsesH1 antihistamine (nonsedating)
  • UsesStandard substrate in evaluating enzyme Preparations contg b-glucosidase: Weidenhagen, Z. Ver. Zucker-Ind. 79, 591 (1929).
  • DefinitionChEBI: An aryl beta-D-glucoside that is the beta-D-glucoside of the phenolic hydroxy group of salicyl alcohol.
  • Purification MethodsCrystallise D(-)-salicin from EtOAc, EtOH or water and sublime it at 190-195o/12mm. [Armour et al. J Chem Soc 412 1961, IR: Pearl & Darling J Org Chem 24 731 1959, Beilstein 17 III/IV 2986, 17/7 V 113.]
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