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Ethyl bromodifluoroacetate

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Ethyl bromodifluoroacetate Basic information
Ethyl bromodifluoroacetate Chemical Properties
  • Boiling point:112 °C700 mm Hg(lit.)
  • Density 1.583 g/mL at 25 °C(lit.)
  • refractive index n20/D 1.387(lit.)
  • Flash point:70 °F
  • storage temp. Flammables area
  • solubility Soluble in most organic solvents.
  • form Liquid
  • Specific Gravity1.583
  • color Clear colorless to slightly yellow
  • BRN 1906095
  • InChIKeyIRSJDVYTJUCXRV-UHFFFAOYSA-N
  • CAS DataBase Reference667-27-6(CAS DataBase Reference)
  • NIST Chemistry ReferenceEthyl bromodifluoroacetate(667-27-6)
Safety Information
  • Hazard Codes C,F,Xi
  • Risk Statements 10-34-36
  • Safety Statements 26-36/37/39-45-16-27
  • RIDADR UN 2924 3/PG 2
  • WGK Germany 3
  • Hazard Note Irritant/Flammable
  • TSCA No
  • HazardClass 3
  • PackingGroup II
  • HS Code 29159000
MSDS
Ethyl bromodifluoroacetate Usage And Synthesis
  • Chemical Propertiesclear colorless to slightly yellow liquid
  • UsesEthyl bromodifluoroacetate is usually used in the preparation of substituted ethyl 2′-pyridyldifluoroacetates,4-alkoxymethyl- and 4-aryloxymethyl-3,3-difluoropiperidines,α,α-difluoro-β-lactams,mono- and difluoromethylated phenanthridine derivatives.
  • UsesEfficient difluoroalkylation of aryl boronic acids via palladium catalysis. Novel, moisture-stable bromodifluoromethylated phosphonate, ester, and amide. Efficient coupling with aryl boronic acids via Pd catalysis.
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