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Sodium thiomethoxide

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Sodium thiomethoxide Basic information
Sodium thiomethoxide Chemical Properties
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MSDS
Sodium thiomethoxide Usage And Synthesis
  • Chemical PropertiesVery faint yellowish red clear liquid
  • UsesSodium thiomethoxide is a strong nucleophile used for the synthesis of methyl aryl sulfides from halo-arenes. Alkanethiolates are efficient reagents for SN2 dealkylation of esters and aryl ethers.
  • Purification MethodsDissolve the salt (10g) in EtOH (10mL) and add Et2O (100mL). Cool and collect the precipitate, wash it with Et2O and dry it in a vacuum. It is a white powder which is very soluble in EtOH and H2O. [Billmann & Jensen Bull Soc Chim Fr 3 2318 1936, Beilstein 1 III 1212.]
Sodium thiomethoxide Preparation Products And Raw materials
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