ChemicalBook Product Catalog Flavors and fragrances Synthetic fragrances Carboxylic acids and esters Aromatic carboxylic acid ester BENZYL PHENYLACETATE

BENZYL PHENYLACETATE

Product NameBENZYL PHENYLACETATE
CAS102-16-9
MFC15H14O2
MW226.27
EINECS203-008-4
MOL File102-16-9.mol

Chemical Properties

Melting point	51-52 °C
Boiling point	317-319 °C(lit.)
Density	1.097 g/mL at 25 °C(lit.)
vapor pressure	0.015Pa at 25℃
refractive index	n20/D 1.555(lit.)
FEMA	2149 \| BENZYL PHENYLACETATE
Flash point	200 °F
color	Colorless to Almost colorless
Odor	at 100.00 %. sweet floral jasmin cocoa
Odor Type	floral
biological source	synthetic
Water Solubility	18.53mg/L at 25℃
JECFA Number	849
Major Application	flavors and fragrances
Cosmetics Ingredients Functions	PERFUMING
InChI	1S/C15H14O2/c16-15(11-13-7-3-1-4-8-13)17-12-14-9-5-2-6-10-14/h1-10H,11-12H2
InChIKey	MIYFJEKZLFWKLZ-UHFFFAOYSA-N
SMILES	O=C(Cc1ccccc1)OCc2ccccc2
LogP	3.478 at 25℃
CAS DataBase Reference	102-16-9(CAS DataBase Reference)
NIST Chemistry Reference	Benzeneacetic acid, phenylmethyl ester(102-16-9)
EPA Substance Registry System	Benzeneacetic acid, phenylmethyl ester (102-16-9)

Safety Information

Hazard Codes	N
Risk Statements	50/53
Safety Statements	60-61
RIDADR	UN 3082 9 / PGIII
WGK Germany	2
TSCA	TSCA listed
HS Code	29163990
Storage Class	10 - Combustible liquids
Hazard Classifications	Aquatic Acute 1
Toxicity	The acute oral LD₅₀ was reported as > 5000 mg/kg in the rat. The acute dermal LD₅₀ was reported as > 10 ml/kg in the rabbit

MSDS

Provider	Language
SigmaAldrich	English

Usage And Synthesis

Chemical Properties

Benzyl phenylacetate has a sweet, floral (jasmine-rose) odor and a slight honey-like taste.

Chemical Properties

Colorless liquid; honeylike odor.Soluble in alcohol. Combustible.

Occurrence

Not reported found in nature; phenylacetic acid, on the other hand, has been reported in several essential oils.

Uses

Perfumery and flavors.

Preparation

By direct esterification of benzyl alcohol with phenylacetic acid.

Definition

ChEBI: Phenylmethyl benzeneacetate is a carboxylic ester. It is functionally related to a benzyl alcohol.

Application

Benzyl phenylacetate is used quite commonly in flavor formulations, for imitation Butter, Caramel, Fruit,Honey, etc. Again here, its fixative effect makes it suitable for flavors for hard candy, baked goods, etc., since this ester has good heat-stability.

Synthesis Reference(s)

Synthesis, p. 138, 1982 DOI: 10.1055/s-1982-29718
Tetrahedron Letters, 27, p. 55, 1986 DOI: 10.1016/S0040-4039(00)83938-6

General Description

Clear colorless liquid with a honey-like odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

BENZYL PHENYLACETATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. BENZYL PHENYLACETATE is sensitive to excessive light and heat.

Fire Hazard

BENZYL PHENYLACETATE is probably combustible.

Solubility in organics

Poorly soluble in Propylene glycol, soluble in alcohol and oils.

Preparation Products And Raw materials

BENZYL PHENYLACETATE Supplier

BENZYL PHENYLACETATE manufacturers

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