Lithium perchlorate

• Product Name:Lithium perchlorate
• Synonyms: Lithium perchlorate (LiClO4) Lithiumperchlora Lithium perchlorate, for analysis, 99+% LITHIUM PERCHLORATE, ANHYDROUS BIO-REFINED LITHIUM PERCHLORATE, ANHYDROUS REAGENT (ACS) LITHIUM PERCHLORATE, BATTERY GRADE Lithiumperchlorate,anhydrous,95+%(ACS) Lithiumperchlorat
• CAS:7791-03-9
• MF:ClLiO4
• MW:106.39
• EINECS:232-237-2
• Mol File:7791-03-9.mol
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Lithium perchlorate (LiClO4) is sufficiently soluble (beyond 1Min organic solvents, e.g., EC/DMC) and forms electrolyte solutions with good conductivity (about 9 mS·cm?1 in EC/DMC at ambient temperature). In organic solvents LiClO4 forms thicker solid electrolyte interface (SEI) layers than LiPF6 or LiBF4, but they are less resistive. This fact is attributed to the highly resistive LiF on the surface which is formed by hydrogen fluoride (HF) generated by hydrolysis of fluorine-containing anions, for example, LiBF4 and LiPF6, with traces of moisture and the existing SEI layer [62, 63]. Furthermore, it has a high anodic stability of up to 5.1 V on LiMn2O4 in EC/DMC and is less hygroscopic than LiPF6. Despite its many advantages, the high oxidation state of chlorine (VII) in ClO4 ? results in problems. LiClO4 solutions are thermally unstable and show explosion risks, especially in ethers.