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PENTACHLOROBENZENE

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<em>Biological.</em> In activated sludge, <0.1% mineralized to carbon dioxide after 5 days (Freitag et al., 1985). From the first-order biotic and abiotic rate constants of pentachlorobenzene in estuarine water and sediment/water systems, the estimated biodegradation half-lives were 4.6–6.5 and 6.0–7.6 days, respectively (Walker et al., 1988)<br /><em>Photolytic.</em> UV irradiation (λ = 2537 ?) of pentachlorobenzene in a hexane solution for 3 hours produced a 50% yield of 1,2,4,5-tetrachlorobenzene and a 13% yield of 1,2,3,5- tetrachlorobenzene (Crosby and Hamadmad, 1971). Irradiation (λ ≥285 nm)<br />A carbon dioxide yield of 2.0% was achieved when pentachlorobenzene adsorbed on silica gel was irradiated with light (λ >290 nm) for 17 hours (Freitag et al., 1985).<br />The experimental first-order decay rate for pentachlorobenzene in an aqueous solution containing a nonionic surfactant micelle (Brij 58, a polyoxyethylene cetyl ether) and illuminated by a photoreactor equipped with 253.7-nm monochromatic UV lamps, is 1.47 × 10–2/sec. The corresponding half-life is 47 seconds. Photoproducts reported include, all<br />tetra-, tri- and dichlorobenzenes, chlorobenzene, benzene, phenol, hydrogen and chloride ions (Chu and Jafvert, 1994)

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