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Boron trifluoride suppliers
- CAS:
- 7637-07-2
- MF:
- BF3
- MW:
- 67.81
Properties
- Melting point::
- −127 °C(lit.)
- Boiling point::
- −100 °C(lit.)
- Density :
- 0.87 g/mL at 20 °C
- vapor density :
- 2.38 (21 °C, vs air)
- vapor pressure :
- >1 mmHg at 20 °C
- refractive index :
- n
20/D 1.38
- Flash point::
- 4°C
- storage temp. :
- 2-8°C
- solubility :
- soluble in H2O
- form :
- Liquid
- color :
- Colorless
- Odor:
- Pungent odor detectable at 1.5 ppm
- Water Solubility :
- MAY DECOMPOSE
- Sensitive :
- Moisture Sensitive
- Merck :
- 14,1349
- Exposure limits:
- ACGIH: TWA 0.1 ppm(2.5 mg/m3); Ceiling 0.7 ppm
OSHA: Ceiling 1 ppm(3 mg/m3)
NIOSH: IDLH 25 ppm(250 mg/m3); Ceiling 1 ppm(3 mg/m3)
- LogP:
- 1.070 (est)
SecurityInformation
- Symbol(GHS) :
-
GHS04,GHS05,GHS06
- Signal word :
- Danger
- Hazard statements :
- H280-H314-H330
- Precautionary statements :
- P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P410+P403
- Hazard Codes :
- T+,C,T,F
- Risk Statements :
- 14-26-35-39/23/24/25-24/25-11-67-41-10-37-22
- Safety Statements :
- 9-26-28-36/37/39-45-28A-16
- OEL:
- Ceiling: 1 ppm (3 mg/m3)
- RIDADR :
- UN 3286 3/PG 2
- WGK Germany :
- 3
- RTECS :
- ED2275000
- F :
- 21
- Hazard Note :
- Corrosive/Toxic
- TSCA :
- Yes
- DOT Classification:
- 2.3, Hazard Zone B (Gas poisonous by inhalation)
- HazardClass :
- 2.3
- Toxicity:
-
LC50 inhal (rat) 387 ppm (1070 mg/m3; 1 h)
PEL (OSHA) 1 ppm (3 mg/m3; ceiling)
TLV (ACGIH) 1 ppm (3 mg/m3; ceiling)
- IDLA:
- 25 ppm
- Use:
- Boron trifluoride (and organic complexes such as BF3-etherate) are extremel corrosive substances that are destructive to all tissues of the body. Upon contact with moisture in the skin and other tissues, these compounds react to form hydrofluoric acid and fluoroboric acid, which cause severe burns. Boron trifluoride gas is extremely irritating to the skin, eyes, and mucous membranes. Inhalation of boron trifluoride can cause severe irritation and burning of the respiratory tract, difficult breathing, and possibly respiratory failure and death. Exposure of the eyes to BF can cause severe burns and blindness. This compound is not considered to have adequate warning properties. Boron trifluoride has not been found to be carcinogenic or to show reproductive or developmental toxicity in humans. Chronic exposure to boron trifluoride gas can cause respiratory irritation and dama
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