구리 프탈로시아닌

한글명:구리 프탈로시아닌

카스 번호147-14-8

상품명:Copper(II) phthalocyanine

CBNumberCB6255035

분자식C32H16CuN8

포뮬러 무게576.07

MOL 파일147-14-8.mol

동의어(한글)

구리프탈로시아닌

청색404호

화학적 성질

녹는점	600°C (dec.)
밀도	1.62[at 20℃]
저장 조건	Inert atmosphere,Room Temperature
용해도	insoluble in H2O, ethanol; soluble in concHSO 4
색상 색인 번호	74160
물리적 상태	미세 결정성 분말
색상	진한 파란색
냄새	냄새 없는
수용성	20°C에서 <0.1g/100mL
최대 파장(λmax)	602nm(CHCl3)(lit.)
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
Merck	14,2520
BRN	4121848
노출 한도	ACGIH: TWA 1 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
InChIKey	XCJYREBRNVKWGJ-UHFFFAOYSA-N
LogP	-1 at 23℃
NIST	Copper phthalocyanine(147-14-8)
EPA	C.I. Pigment Blue 15 (147-14-8)
Absorption	λmax 678 nm (DMF)

위험 및 안전 성명

안전지침서

22-24/25

WGK 독일

RTECS 번호

GL8510000

TSCA

Yes

HS 번호

32041300

유해 물질 데이터

147-14-8(Hazardous Substances Data)

독성

LD50 intraperitoneal in rat: > 3gm/kg

NFPA 704:

	0
0		0

구리 프탈로시아닌 MSDS

구리 프탈로시아닌 화학적 특성, 용도, 생산

개요
Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor?with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV).?Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer . CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device . Device stability was achieved by?depositing a copper phthalocyanine CuPc hole-injection layer?HIL on the ITO anode.
화학적 성질
dark blue fine crystalline powder
용도
Copper(II) phthalocyanine are involved in the study of photosensitizer chemistry for uniform polymerization, luminescence chemistry and spectrophotometric analysis, organic synthesis and polymerization. This pigment is used in enamels, linoleum, inks, plastics, and rubber goods. Photoisomerizable phthalocyanines are used in rewritable CD or DVD printing.Other applications in organic solar cells, biosensitizers and display devices such as OLED , OTFT, Wearable Display, and e-paper.
주요 응용
Copper(II) phthalocyanine, known as CuPc, has been used as an electron donor with fullerene-C60 or phenyl-C61-butyric acid methyl ester (PCBM) in vacuum-deposited organic photovoltaics (OPV). Power conversion efficiency of about 1% has been achieved [2] and improved efficiency of 4% with pentacene-doped CuPc layer.
CuPc has also been used as a hole-injection material for light-emitting diodes. It has been reported that a thin CuPc layer may effectively enhance the hole injection from the anode to the emissive-polymer layer, resulting in a dramatic decrease of operating voltage of the device. Device stability was achieved by depositing a copper phthalocyanine CuPc hole-injection layer HIL on the ITO anode. The improved stability could be contributed to the good match of its highest-occupied molecular orbital (HOMO) level to the work function of ITO, and the improved wetting property of organic materials on ITO. Moreover, CuPc has very weak absorption of light, with wavelengths from 400 to 500 nm, making it suitable for use in blue and green OLEDs.
Effective electron-blocking was also observed for inorganic–organic hybrid perovskite solar cells when CuPc-doped spiro-OMeTAD was used as the hole-transporting layer.
일반 설명
Copper(II) phthalocynaine (CuPc) is a metal phthalocyanine dye that acts as a p-type semiconductor. It has a charge mobility of 10^-4 cm²/Vs. It forms a chemically stable thin film that exhibits photoconductivity and catalytic activity.
Purification Methods
Precipitate it twice from conc H2SO4 by slow dilution with water. It has also been purified by two or three sublimations at 580o in an argon flow at 300-400Pa. [Beilstein 26 III/IV 4256.]

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