벤조[G,H,I]페릴렌

한글명:벤조[G,H,I]페릴렌

카스 번호191-24-2

상품명:1,12-BENZOPERYLENE

CBNumberCB4708830

분자식C22H12

포뮬러 무게276.33

MOL 파일191-24-2.mol

동의어(한글)

벤조페릴렌

벤조[G,H,I]페릴렌

화학적 성질

녹는점	277-279 °C(lit.)
끓는 점	>500 °C(lit.)
밀도	1.1847 (estimate)
증기압	1.10 (extrapolated from vapor pressures determined at higher temperatures, Pupp et al., 1974)1.04 (Murray et al., 1974)
굴절률	1.9800 (estimate)
인화점	-18 °C
저장 조건	room temp
용해도	벤젠, 염화메틸렌, 아세톤을 포함한 대부분의 용매(US EPA, 1985)에 용해됩니다.
산도 계수 (pKa)	>15 (Christensen et al., 1975)
물리적 상태	바늘 모양의 결정 또는 결정성 분말
색상	노란색
수용성	0.137ug/L(25 ºC)
BRN	1913029
Henry's Law Constant	1.88, 2.66, 5.13, 5.33, 6.51, and 8.59 at 10.0, 20.0, 35.0, 40.1, 45.0, and 55.0 °C, respectively (wetted-wall column, ten Hulscher et al., 1992)
안정성	안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다.
InChIKey	GYFAGKUZYNFMBN-UHFFFAOYSA-N
IARC	3 (Vol. 92, Sup 7) 2010
EPA	Benzo[g,h,i]perylene (191-24-2)

위험 및 안전 성명

위험품 표기	N,Xn,F
위험 카페고리 넘버	50/53-40-67-65-38-11-36/37/38-20
안전지침서	60-61-36/37-24/25-23-62-33-25-16-9
유엔번호(UN No.)	UN 3077 9/PG 3
WGK 독일	3
RTECS 번호	DI6200500
F 고인화성물질	8-10
위험 등급	9
포장분류	III
HS 번호	29029090
유해 물질 데이터	191-24-2(Hazardous Substances Data)
독성	mma-sat 2 mg/plate/48H FCTXAV 17,141,79

그림문자(GHS)

벤조[G,H,I]페릴렌 화학적 특성, 용도, 생산

화학적 성질
solid
용도
Research chemical. Derived from industrial and experimental coal gasification operations where the maximum concentration detected in coal tar streams was 2.7 mg/m³ (Cleland, 1981).
일반 설명
Colorless to white crystalline solid. Water insoluble.
공기와 물의 반응
Insoluble in water.
반응 프로필
Vigorous reactions, sometimes amounting to explosions, can result from the contact between aromatic hydrocarbons, such as 1,12-BENZOPERYLENE, and strong oxidizing agents. They can react exothermically with bases and with diazo compounds. Substitution at the benzene nucleus occurs by halogenation (acid catalyst), nitration, sulfonation, and the Friedel-Crafts reaction.
건강위험
Inhalation of material may be harmful. Contact may cause burns to skin and eyes. Inhalation of Asbestos dust may have a damaging effect on the lungs. Fire may produce irritating, corrosive and/or toxic gases. Some liquids produce vapors that may cause dizziness or suffocation. Runoff from fire control may cause pollution.
화재위험
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
Safety Profile
Questionable carcinogen.Mutation data reported. When heated to decomposition itemits acrid smoke and irritating fumes.
Carcinogenicity
Subcutaneous or dermal administration (repeated administration and initiation–promotion protocols) of benzo[ghi]perylene to mice gave negative results. Intrapulmonary injection into rats gave results considered to be inadequate for evaluation.
환경귀착
Biological. Based on aerobic soil die away test data at 10 to 30 °C, the estimated half-lives ranged from 590 to 650 d (Coover and Sims, 1987).
Groundwater. Based on aerobic soil die away test data at 10 to 30 °C, the estimated half-lives ranged from 3.23 to 3.56 yr (Coover and Sims, 1987).
Photolytic. The atmospheric half-life was estimated to range from 0.321 to 3.21 h (Atkinson, 1987). Behymer and Hites (1985) determined the effect of different substrates on the rate of photooxidation of benzo[ghi]perylene using a rotary photoreactor. The photolytic half-lives of benzo[ghi]perylene using silica gel, alumina, and fly ash were 7.0, 22, and 29 h, respectively.
Chemical/Physical. At influent concentrations of 1.0, 0.1, 0.01, and 0.001 mg/L, the GAC adsorption capacities were 10.7, 4.6, 2.0, and 0.85 mg/g, respectively (Dobbs and Cohen, 1980).
Purification Methods
It forms light green crystals on recrystallisation from *C6H6 or xylene and sublimes at 320-340o/0.05mm [UV: Hopff & Schweizer Helv Chim Acta 42 2315 1959, Clar Chem Ber 65 846 1932, Fluoresc. Spectrum: Bowen & Brocklehurst J Chem Soc 3875 1954]. It also recrystallises from propan-1-ol [Altman & Ginsburg J Chem Soc 466 1959]. The 1,3,5-Trinitrobenzene complex has m 310-313o (deep red crystals from *C6H6), the picrate has m 267-270o (dark red crystals from *C6H6), and the styphnate (2,4,6-trinitroresorcinol complex) has m 234o (wine red crystals from *C6H6). [Beilstein 5 IV 2766.]

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