과산화 수소

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Danger

• 유해·위험 문구

  H302：삼키면 유해함

  H315：피부에 자극을 일으킴

  H318：눈에 심한 손상을 일으킴

  H335：호흡 자극성을 일으킬 수 있음

  H412：장기적 영향에 의해 수생생물에 유해함

• 예방조치문구

  P261：분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.

  P273：환경으로 배출하지 마시오.

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

  P301+P312：삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.

  P302+P352：피부에 묻으면 다량의 물로 씻으시오.

  P305+P351+P338：눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

과산화 수소 MSDS

• Hydrogen peroxide

과산화 수소 화학적 특성, 용도, 생산

• 개요

  과산화수소는 발생기 산소를 발생시키는 불안정한 물질 로 대부분의 용도는 이 발생기 산소를 이용하는 것입니다. 본 제품의 대표적인 용도는 표백제와 산화 제로 대량 수요업종은 제지펄프, 염색 가공업종입니다. 환경규제가 강화되고 있는 오늘날, 과산화수 소의 무공해특성은 더욱더 그 진가를 발휘하고 있습니다.

• 용도

  과산화수소는 표백제, 산화제, 유도체제조등에 광범위하 게 사용되는 화학물질입니다. 과산화수소의 대표적인 용도는 표백제로 섬유염색공업, 제지펄프공업에 서 대량으로 사용되고 있으며, 최근에는 산화제로서 인쇄기판 에칭용, 반도체 제조용으로 그 수요가 확대되고 있습니다. 그리고 본 제품의 환경친화적 특성은 폐수처리분야의 수요를 폭발적으로 증대시 키고 있습니다.

• 순도시험

    (1) 유리산 : 이 품목 3mL에 새로 끓여서 식힌 물을 가하여 50mL로 하고 0.02N 수산화나트륨용액 1mL를 가한 다음 페놀프탈레인시액 3방울을 가할 때, 홍색을 나타내어야 한다.

    (2) 비소 : 이 품목을 비소시험법에 따라 시험할 때, 그 양은 4.0ppm 이하이어야 한다.

    (3) 납 : 이 품목 5.0g에 물 10mL를 가하고 이를 조금씩 비이커에 취하여 수욕상에서 기포생성이 끝날 때까지 조용히 가온한 다음 0.5N 질산으로 25m1로 한 액을 시험용액으로 하여 원자흡광광도법 또는 유도결합플라즈마발광광도법에 따라 시험할 때, 그 양은 4.0ppm 이하이어야 한다.

    (4) 주석 : 이 품목 5.0g에 물 10mL를 가하고 이를 조금씩 비이커에 취하여 수욕상에서 기포생성이 끝날 때까지 조용히 가온한 다음 1N 염산으로 25m1로 한 액을 시험용액으로 하여 원자흡광광도법 또는 유도결합플라즈마발광광도법에 따라 시험할 때, 그 양은 10ppm 이하이어야 한다.

    (5) 철 : 이 품목 5.0g에 물 10mL를 가하고 이를 조금씩 비이커에 취하여 수욕상에서 기포생성이 끝날 때까지 조용히 가온한 다음 0.5N 질산으로 25m1로 한 액을 시험용액으로 하여 원자흡광광도법 또는 유도결합플라즈마발광광도법에 따라 시험할 때, 그 양은 0.5ppm 이하이어야 한다.

    (6) 증발잔류물 : 이 품목 50g을 정밀히 달아 조금씩 백금도가니에 넣고 수욕상에서 조용히 가열하여 증발건고한 다음 잔류물을 105℃에서 1시간 건조할 때, 그 양은 3mg 이하이어야 한다.

    (7) 인산염 : 이 품목 8mL에 물 10mL 및 염산 3mL를 가하여 수욕상에서 조용히 가열하여 증발건고하고 잔류물에 더운물 약 30mL를 가하여 녹이고 식힌 다음 다시 물을 가하여 50mL로 하여 시험용액으로 한다. 시험용액 5mL를 네슬러관에 취하고 여기에 황산(1→6) 4mL 및 몰리브덴산암모늄용액(1→20) 1mL를 가하여 잘 흔들어 섞고 3분간 방치한 다음 1-아미노-2-나프톨-4-설폰산시액 1mL를 가하여 흔들어 섞고 60℃의 수욕 중에 30분간 가온한 다음 흐르는 물로 식힐 때, 나타내는 청색은 인산염표준용액 5mL를 네슬러관에 취하여 시험용액과 같이 조작한 액보다 진하여서는 아니 된다.

• 확인시험

    (1) 이 품목은 산성이다.

    (2) 이 품목의 수용액(1→10) 1mL에 묽은황산 5mL 및 과망간산칼륨시액 1mL를 가하면 거품이 일고 시액의 색은 없어진다.

    (3) 이 품목은 확인시험법 중 과산화물의 반응을 나타낸다.

• 정량법

    이 품목 약 1g을 정밀히 달아 물을 가하여 250mL로 하고 그 중 25mL에 묽은황산 10mL를 가하여 0.1N 과망간산칼륨용액으로 적정한다.

  0.1N 과망간산칼륨용액 1mL ＝ 1.701mg H₂O₂

• 개요

  Hydrogen peroxide (H2O2) is a strong oxidizing agent that is used extensively in industry and medicine. It is usually available as aqueous solutions in concentrations of 3, 30 or 90 percent by weight. The 3 percent solution is used as a topical antiseptic and cleansing agent, and as a constituent in mouthwashes, dentifrices and sanitary lotions; the 30 percent as an effective bleaching agent and for other industrial uses; and the 90 percent as a vigorous oxidizer of rocket fuels. The anhydrous form is a colorless, bittertasting liquid with an ozone-like odor. In the absence of stabilizing agents (e.g., phosphates, tin), hydrogen peroxide solutions are unstable and decompose upon standing, agitation, exposure to light, or heating. Hydrogen peroxide reacts vigorously with many oxidizing as well as reducing agents. Concentrated solutions are highly caustic to the skin. In addition to its effectiveness as a bleach, hydrogen peroxide has proved to be a useful antimicrobial agent. This latter property has been utilized in some countries as a preservative of milk and whey.

• 화학적 성질

  Colorless liquid; pure compound or 90% solution unstable; bitter taste; density 1.463 g/mL; boils at 150.2°C; freezes at –0.43°C; vapor pressure 9.9 torr at 50°C and 121.5 torr at 100°C; viscosity 1.245 centipoise at 20°C; surface tension 80.4 dyn/cm at 20°C; miscible with water in all proportions; soluble in ether; densities of 30%, 70%, and 90% H2O2 solutions are 1.1081, 1.2839 and 1.3867 g/mL, respectively, at 25°C; freezing points at these concentrations are –25.7°C, –40.3°C and –11.5°C, respectively; and their boiling points are 106.2°C, 125.5°C and 141.3°C, respectively; decomposed by many organic solvents; pKa at 25°C is 11.62.

• 물리적 성질

  Colorless liquid; pure compound or 90% solution unstable; bitter taste; den-sity 1.463 g/mL; boils at 150.2°C; freezes at -0.43°C; vapor pressure 9.9 torrat 50°C and 121.5 torr at 100°C; viscosity 1.245 centipoise at 20°C; surfacetension 80.4 dyn/cm at 20°C; miscible with water in all proportions; soluble inether; densities of 30%, 70%, and 90% H₂O₂solutions are 1.1081, 1.2839 and1.3867 g/mL, respectively, at 25°C; freezing points at these concentrations are-25.7°C, -40.3°C and -11.5°C, respectively; and their boiling points are106.2°C, 125.5°C and 141.3°C, respectively; decomposed by many organic sol-vents; pKaat 25°C is 11.62.

• 역사

  Hydrogen peroxide was prepared first by Thenard in 1818. It has many industrial applications. Aqueous solutions at varying concentrations are used for bleaching fabrics, silks, furs, feathers and hair; as a dough conditioner; and a bleaching and oxidizing agent in foods; for cleaning metals; as a laboratory reagent for oxidation; as an antiseptic; in sewage and wastewater treatment; and in preparation of inorganic and organic peroxides. An 80% concentrated solution is used in rocket propulsion.

• 용도

  hydrogen peroxide is a bleaching and oxidizing agent, detergent, and antiseptic. It is generally recognized as a safe preservative, germ killer, and skin bleacher in cosmetics. If used undiluted, it can cause burns of the skin and mucous membranes.

• 정의

  hydrogen peroxide: A colourlessor pale blue viscous unstable liquid,H₂O₂; r.d. 1.44; m.p. –0.41°C; b.p.150.2°C. As with water, there is considerablehydrogen bonding in theliquid, which has a high dielectricconstant. It can be made in the laboratoryby adding dilute acid to bariumperoxide at 0°C. Large quantitiesare made commercially by electrolysisof KHSO₄.H₂SO₄ solutions. Anotherindustrial process involvescatalytic oxidation (using nickel, palladium,or platinum with an anthraquinone)of hydrogen and waterin the presence of oxygen. Hydrogenperoxide readily decomposes in lightor in the presence of metal ions togive water and oxygen. It is usuallysupplied in solutions designated byvolume strength. For example, 20-volume hydrogen peroxide wouldyield 20 volumes of oxygen per volumeof solution. Although the peroxidesare formally salts of H2O2, thecompound is essentially neutral.Thus, the acidity constant of the ionizationH₂O₂ + H₂O ?H₃O⁺ + HO_2–is 1.5 × 10^-12 mol dm^-3. It is a strongoxidizing agent, hence its use as amild antiseptic and as a bleachingagent for cloth, hair, etc. It has alsobeen used as an oxidant in rocketfuels.

• 생산 방법

  From 1920 to 1950, the primary method of production was electrolysis. One process involved passing electric current through sulfuric acid to produce the peroxydisulfate ion (S2O8 2-), which was then hydrolyzed to H2O2: 2H₂O + S₂O₈^2- (aq) 2H₂SO₄^-(aq) + H₂O₂(aq).the relatively high cost of electricity of this method encouraged a search for a more economical production process. Hydrogen peroxide is currently produced on a large scale using the anthraquinone autooxidation procedure, which was developed in the 1940s. In this process, an anthraquinone, typically 2-ethyl-anthraquinone, is hydrogenated to a hydroquinone (2-ethyl-anthrahydroquinone) then reoxidized back to the anthraquinone (2-ethyl-anthraquinone) while forming hydrogen peroxide . A metal palladium or nickel catalyst is used to convert the anthraquinone to the hydroquinone, followed by autooxidation in air to generate hydrogen peroxide. The anthraquinone and hydrogen peroxide are separated; the former is recycled to repeat the process while the hydrogen peroxide is purified.

• 화학 반응

  Hydrogen peroxide reacts with many compounds, such as borates, carbonates, pyrophosphates, sulfates, silicates, and a variety of organic carboxylic acids, esters, and anhydrides to give peroxy compounds or peroxyhydrates. A number of these compounds are stable solids that hydrolyze readily to give hydrogen peroxide in solution.

• 일반 설명

  A colorless liquid dissolved in water. Vapors may irritate the eyes and mucous membranes. May violently decompose on contact with most common metals and their compounds. Contact with combustible material may result in spontaneous ignition. Corrosive to tissue. Under exposure to fire or heat containers may violently rupture due to decomposition. Used to bleach textiles and wood pulp, in chemical manufacturing, food processing, and in water purification.

• 공기와 물의 반응

  Water soluble.

• 반응 프로필

  The hazards associated with the use of HYDROGEN PEROXIDE(especially highly concentrated solutions) are well documented. There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. Contamination of concentrated peroxide causes the possibility of explosion. Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. Solvents(acetone, ethanol, glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with concentration. Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)].

• 위험도

  Hydrogen peroxide is a strong oxidizing agent. Concentrated solutions, even a 30% aqueous solution, should be handled carefully. The compound decomposes violently in the presence of trace impurities. Inhibitors are, therefore, added at trace levels to prevent decomposition. Explosion can occur when concentrated solutions are heated or brought in contact with a number of organic substances that are readily oxidizable or that form organic peroxides, such as alcohols, aldehydes, ketones, anhydrides, and carboxylic acids (Patnaik, P. 1999. A Comprehensive Guide to the Hazardous Properties of Chemical Substances, 2nd ed. New York: John Wiley & Sons). Also, reactions with metals, metal alloys, a number of metal salts and oxides, and concentrated mineral acids can proceed to explosive violence.

• 건강위험

  Contact with aqueous concentrations of less than 50% cause skin irritation, but more concentrated solutions of H202 are corrosive to the skin. At greater than 10% concentration, hydrogen peroxide is corrosive to the eyes and can cause severe irreversible damage and possibly blindness. Hydrogen peroxide is moderately toxic by ingestion and slightly toxic by inhalation. This substance is not considered to have adequate warning properties. Hydrogen peroxide has not been found to be carcinogenic in humans. Repeated inhalation exposures produced nasal discharge, bleached hair, and respiratory tract congestion, with some deaths occurring in rats and mice exposed to concentrations greater than 67 ppm

• 화재위험

  Hydrogen peroxide is not flammable, but concentrated solutions may undergo violent decomposition in the presence of trace impurities or upon heating

• 인화성 및 폭발성

  Hydrogen peroxide is not flammable, but concentrated solutions may undergo violent decomposition in the presence of trace impurities or upon heating.

• 색상 색인 번호

  Hydrogen peroxide is an oxidizing agent used as a topi- cal antiseptic, and as part of permanent hair-dyes and color-removing preparations, and as a neutralizing agent in permanent waving. The concentration of the hydrogen peroxyde solution is expressed in volume or percentage: Ten volumes correspond to 3%. It is an irritant.

• Toxicology

  Hydrogen peroxide is used as an agent to reduce the number of bacteria in dairy products or other foodstuffs. In the dairy industry, hydrogen peroxide also has been used as a substitute for heat pasteurization in the treatment of milk and as a direct preservative in keeping the quality of the milk. In Japan, it has been used as a preservative for fish-paste products. Hydrogen peroxide also has a bleaching effect. The use of highly pure hydrogen peroxide in manufactured cheese has been approved by the United States Food and Drug Administration (industrial grade hydrogen peroxide is usually a 3–35% aqueous solution; a commercial home product is a 3% aqueous solution).
  Acute toxicities (LD50) of hydrogen peroxide for rats are 700 mg/kg/b.w. and 21 mg/kg/b.w. by subcutaneous injection and intravenous injection, respectively. When large amounts of hydrogen peroxide were injected directly into the stomachs of rats, weight and blood protein concentrations were changed slightly. When hydrogen peroxide was mixed with feed, however, no abnormalities were observed. The use of bactericides has been limited due to their toxicity to humans, and only hydrogen peroxide currently is recognized for use.

• Carcinogenicity

  Chronic studies in mice found adenomas and carcinomas of the duodenum after oral administration. The IARC has determined that there is limited evidence in experimental animals for the carcinogenicity of hydrogen peroxide and inadequate evidence in humans.

• 저장

  Use extreme care when carrying out reactions with hydrogen peroxide because of the fire and explosion potential (immediate or delayed). The use of safety shields is advisable, and is essential for experiments involving concentrated (>50%) solutions of hydrogen peroxide. Sealed containers of hydrogen peroxide can build up dangerous pressures of oxygen, owing to slow decomposition.

• Purification Methods

  The 30% material has been steam distilled using distilled water. Gross and Taylor [J Am Chem Soc 72 2075 1950] made 90% H2O2 approximately 0.001M in NaOH and then distilled it under its own vapour pressure, keeping the temperature below 40o, the receiver being cooled with a Dry-ice/isopropyl alcohol slush. The 98% material has been rendered anhydrous by repeated fractional crystallisation in all-quartz vessels. EXPLOSIVE IN CONTACT WITH ORGANIC MATERIAL.

• 비 호환성

  Contact with many organic compounds can lead to immediate fires or violent explosions (consult Bretherick for references and examples). Hydrogen peroxide reacts with certain organic functional groups (ethers, acetals, etc.) to form peroxides, which may explode upon concentration. Reaction with acetone generates explosive cyclic dimeric and trimeric peroxides. Explosions may also occur on exposure of hydrogen peroxide to metals such as sodium, potassium, magnesium, copper, iron, and nickel.

• 폐기물 처리

  Excess hydrogen peroxide and waste material containing this substance should be placed in an appropriate container, clearly labeled, and handled according to your institution's waste disposal guidelines. For more information on disposal procedures, see Chapter 7 of this volume.

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