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산화아연

한글명:산화아연

카스 번호1314-13-2

상품명:Zinc oxide

CBNumberCB3853034

분자식OZn

포뮬러 무게81.39

MOL 파일1314-13-2.mol

동의어(한글)

아연겔라틴

아연일산화물

아연화

화학적 성질

녹는점

1975 °C

끓는 점

1949.9°C (estimate)

밀도

5.6

굴절률

2.008~2.029

인화점

27℃

저장 조건

Store at +5°C to +30°C.

용해도

0.0016g/l 불용성

물리적 상태

나노분말

Specific Gravity

5.61

색상

흰색에서 연한 노란색

수소이온지수(pH)

7 (50g/l, H2O, 20℃)(slurry)

냄새

회색 분말 또는 결정의 무취,쓴 맛에 백색

수용성

1.6mg/L(29℃)

Crystal Structure

ZnO type

crystal system

Six sides

Merck

14,10147

Space group

P63mc

Lattice constant

a/nm	b/nm	c/nm	α/o	β/o	γ/o	V/nm3
0.32495	0.32495	0.52069	90	90	120	0.0476

위험 및 안전 성명

위험품 표기

N,Xn,F

위험 카페고리 넘버

50/53-20-43-36/38-20/21/22-67-66-10-11

안전지침서

60-61-7/9-36/37-26-16

유엔번호(UN No.)

UN 3077 9/PG 3

OEB

OEL

TWA: 5 mg/m3, Ceiling: 15 mg/m3

WGK 독일

RTECS 번호

ZH4810000

TSCA

Yes

위험 등급

포장분류

III

HS 번호

28170000

유해 물질 데이터

1314-13-2(Hazardous Substances Data)

독성

LD50 orally in Rabbit: > 5000 mg/kg

IDLA

500 mg/m3

NFPA 704:

	0
1		0

그림문자(GHS)

산화아연 MSDS

산화아연 화학적 특성, 용도, 생산

물성
함량이품목은강열한다음정량할때,산화아연(ZnO)99.0%이상을함유한다.
성상이품목은백색의미세한분말로서냄새가없다.
제품 소개
(1)이품목을강하게가열하면황색을나타내고냉각하면그색은없어진다.
(2)이품목을3N염산에녹인액은확인시험법중아연염의반응을나타낸다.
제품 소개
(1)알칼리도: 이품목2g을20mL의물에현탁시켜1분동안끓이고여과한다음여액에페놀프탈레인시액0.1mL를가할때,적색을나타내어서는 아니 된다.
(2)납 :「메타인산나트륨」의순도시험 (2)에 따라 시험한다(10.0ppm 이하).
(3)카드뮴 :「메타인산나트륨」의 순도시험 (3)에 따라시험한다(3.0ppm 이하).
(4)황화물에 의해 침전되지 아니하는 물질 : 이품목약2g을정밀히달아초산(1→4) 20mL에 녹이고 물을 가해 200mL로 하고 황화암모늄시액을 넣어 아연을 완전히 침전시킨 다음 여과하여 맨 처음 여액을 버리고 나중의 여액 100mL를 미리 항량시킨 백금접시에 옮기어 황산 몇 방울을 넣어 증발건고한 다음 암모늄염이 휘산될 때까지 조심스럽게 800±25℃에서 항량이 될 때까지 강열할 때, 그 양은 5mg 이하이어야 한다.
강열감량 이 품목 약 2g을 정밀히 달아 800±25℃에서 항량이 될 때까지 강열할 때, 그 감량은 1% 이하이어야 한다. 정 량 법 이 품목을 강열한 다음 약 1.5g을 정밀히 달아 염화암모늄 2.5g을 넣은 1N 황산 50mL(필요하면 서서히 가열)에 용해시킨 다음 과량의 황산을 1N 수산화나트륨용액으로 적정한다(지시약 : 메틸오렌지시액).
순도시험

(1) 알칼리도 : 이 품목 2g을 20mL의 물에 현탁시켜 1분동안 끓이고 여과한 다음 여액에 페놀프탈레인시액 0.1mL를 가할 때, 적색을 나타내어서는 아니 된다.
  (2) 납 : 「메타인산나트륨」의 순도시험 (2)에 따라 시험한다(10.0ppm 이하).
  (3) 카드뮴 : 「메타인산나트륨」의 순도시험 (3)에 따라 시험한다(3.0ppm 이하).
  (4) 황화물에 의해 침전되지 아니하는 물질 : 이 품목 약 2g을 정밀히 달아 초산(1→4) 20mL에 녹이고 물을 가해 200mL로 하고 황화암모늄시액을 넣어 아연을 완전히 침전시킨 다음 여과하여 맨 처음 여액을 버리고 나중의 여액 100mL를 미리 항량시킨 백금접시에 옮기어 황산 몇 방울을 넣어 증발건고한 다음 암모늄염이 휘산될 때까지 조심스럽게 800±25℃에서 항량이 될 때까지 강열할 때, 그 양은 5mg 이하이어야 한다.
확인시험

(1) 이 품목을 강하게 가열하면 황색을 나타내고 냉각하면 그 색은 없어진다.
(2) 이 품목을 3N 염산에 녹인 액은 확인시험법 중 아연염의 반응을 나타낸다.
정량법

이 품목을 강열한 다음 약 1.5g을 정밀히 달아 염화암모늄 2.5g을 넣은 1N 황산 50mL(필요하면 서서히 가열)에 용해시킨 다음 과량의 황산을 1N 수산화나트륨용액으로 적정한다(지시약 : 메틸오렌지시액).
1N 황산 1mL ＝ 40.69mg ZnO
화학적 성질
Zinc oxide is an amorphous, white or yellowish-white powder. It is a fine white powder that becomes yellow at temperatures above 3000℃. It is an amphoteric oxide that reacts with acids and dissolves in alkaline solution with formation of zincates. Its density and oil absorption value are 5.6 g/cm³ and 10-25 g oil/100 g ZnO, respectively.
물리적 성질
White or yellowish-white powder; odorless; bitter taste; hexagonal crystal; refractive index 2.008; density 5.606 g/cm³; melts at 1,975°C; practically insoluble in water, 1.6 mg/L at about 30°C; soluble in dilute acids, ammonia solu 990 tion, and alkali hydroxides.
용도
zinc oxide has been used to protect, soothe, and heal the skin. Zinc oxide provides an excellent barrier to the sun and other irritants. It is somewhat astringent, anti-septic, and anti-bacterial. When used in sunscreen preparations, it provides both uVA and uVB protection, and can contribute to and/or increase SPF. At the appropriate particle size, zinc oxide is transparent in the visible light spectrum but opaque in the uVC ranges, thereby avoiding a whitening effect when incorporated into sunscreen preparations. Zinc oxide is included on the FDA’s list of approved sunscreen chemicals. It demonstrates an impressive synergistic effect when combined with organic sunscreens. Zinc oxide is also used when a white color is desired for a product. It is obtained from zinc ore, a commonly found mineral, and is relatively non-allergenic.
제조 방법
Zinc oxide is obtained as an intermediate in recovering zinc from minerals (See Zinc, Recovery). The oxide is prepared by vaporizing zinc metal and oxidation of the zinc vapors with preheated air (French process). The oxide can be produced by other processes. Another method involves roasting franklinite and other ores with coal and then oxidizing the product in air.
주요 응용
ZnO is used primarily for its anti-bacterial and fungicidal properties. Also, in the United States, ZnO is regarded as a Category I skin protectant and a Category III sunscreen.
정의
zinc oxide: A powder, white whencold and yellow when hot, ZnO; r.d.5.606; m.p. 1975°C. It occurs naturallyas a reddish orange ore zincite,and can also be made by oxidizinghot zinc in air. It is amphoteric,forming zincates with bases. It isused as a pigment (Chinese white) and a mild antiseptic in zinc ointments.An archaic name is philosopher’swool.
일반 설명
Crude zinc oxide is a yellow-gray granular solid with no odor. Zinc oxide has a specific gravity of 4.4. Zinc oxide is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Prolonged inhalation of the dust may result in metal fume fever with symptoms of chills, fever, muscular pain, nausea and vomiting.
공기와 물의 반응
Slowly decomposed(hydrolyzed) in water. Insoluble in water.
반응 프로필
ZINC OXIDE is insoluble in water. What little solubility Zinc oxide has yields aqueous solutions that are neutral in pH. Intimate mixtures of zinc oxide and chlorinated rubber with or without hydrocarbons or chlorinated solvent react violently, even explosively upon heating [Chem. Trade J., 1962, 151, 672]. Slow addition of zinc oxide to cover the surface of linseed oil varnish caused generation of heat and ignition, [Chem. Trade J., 1933, 92, 278].
위험도
Exposure to zinc oxide fumes from welding and other operations can cause metal fume fever. Its symptoms are chills, fever, cough, and tightness in the chest.
건강위험
Exposures to zinc oxide metal fume cause several health disorders. The symptoms of toxicity include, but are not limited to, fever, chills, muscle ache, nausea, fever, dry throat, cough; lassitude (weakness, exhaustion), metallic taste, headache, blurred vision, low back pain, vomiting, malaise (vague feeling of discomfort), chest tightness, dyspnea (breathing diffi culty) and decreased pulmonary function. The overexposure to zinc oxide fumes in workplaces produce symptoms known as metal fume fever or “zinc shakes”; an acute, selflimiting condition. Chronic exposure to zinc oxide may cause respiratory tract irritation with nasopharyngitis and laryngitis.
화재위험
Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.
농업용
Zinc oxide (ZnO) is a zinc fertilizer. It is a white powder when cold and yellow when hot, and contains approximately 78% zinc.
Zinc oxide occurs in nature as a reddish-orange colored zincite, and is made by oxidizing hot zinc in air. It is an amphoteric oxide forming zincates, by reacting with bases and zinc salts with acids. It is used as a white pigment and as a mild antiseptic in ointments. An archaic name of zinc oxide is philosopher's wool.
Foliar applications with zinc oxide reduce the foliage damage. Zinc oxide, applied by way of seed coatings, root dips or tree injections, corrects the zinc deficiency. Dipping potato seeds in 2% zinc oxide suspension overcomes zinc deficiency satisfactorily. A similar method is used for pre-plant dipping of the roots of rice seedlings.
Pharmaceutical Applications
The pharmaceutical and cosmetic industries use ZnO in powders and ointments because of its bactericidal properties. It is also used to form dental cements by its reaction with eugenol.
Zinc oxide is used as a raw material for many products: stearates, phosphates, chromates, bromates, organic dithiophosphates, and ferrites (ZnO, MnO, Fe2O3). It is used as a source of zinc in animal feeds and in electrogalvanization . It is also used for desulfurizing gases.
공업 용도
Zinc oxide has many uses. By far the most important is in the rubber industry. Almost half the world’s ZnO is used as an activator for vulcanization accelerators in natural and synthetic rubber. The reactivity of the ZnO is a function of its specific surface area, but is also influenced by the presence of impurities such as lead and sulfates. The ZnO also ensures good durability of the vulcanized rubber, and increases its thermal conductivity. The ZnO content is usually 2–5%.
In paints and coatings, zinc oxide is no longer the principal white pigment, although its superb white color is used by artists. It is used as an additive in exterior paints for wood preservation. It is also utilized in antifouling and anticorrosion paints [2.82]. It improves film formation, durability, and resistance to mildew (having a synergistic effect with other fungicides) because it reacts with acidic products of oxidation and can absorb UV radiation.
In the field of glass, ceramics, and enamels, ZnO is used for its ability to reduce thermal expansion, to lower the melting point, and to increase chemical resistance. It can also be used to modify gloss or to improve opacity.
Materials Uses
The highest purity material is calcined with additives such as Bi2O3 and used in the manufacture of varistors. The photoconducting properties of ZnO are used in photoreproduction processes. Doping with alumina causes a reduction in electrical resistance; hence, it can be used in the coatings on the master papers for offset reproduction.
Zinc oxide is used as a catalyst in organic syntheses (e.g., of methanol), often in conjunction with other oxides. It is present in some adhesive compositions.
Safety Profile
Moderately toxic to humans by ingestion. Poison experimentally by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by inhalation of freshly formed fumes: metal fume fever with chills, fever, tightness of chest, cough, dyspnea, and other pulmonary changes. Mutation data reported. A s h and eye irritant. Has exploded when mixed with chlorinated rubber. Violent reaction with Mg, linseed oil. When heated to decomposition it emits toxic fumes of ZnO. See also ZINC COMPOUNDS.
잠재적 노출
Zinc oxide is primarily used as a white pigment in rubber formulations and as a vulcanizing aid. It is also used as an antiinflammatory agent; in photo copying; paints, chemicals, ceramics, lacquers, and varnishes; as a filler for plastic; in cosmetics; pharmaceuticals, and calamine lotion. Exposure may occur in the manufacture and use of zinc oxide and products, or through its formation as a fume when zinc or its alloys are heated. HC may have been used as a Choking/Pulmonary Agent.
Carcinogenicity
In general, genotoxic studies have not found evidence for mutagenicity of zinc.
운송 방법
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
비 호환성
Incompatible with linseed oil, magnesium. Contact with chlorinated rubber (@ 215C) may cause a violent reaction. Slowly decomposed by water.

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