나트륨 플루오로아세트산

그림문자(GHS)

• 그림문자(GHS)

  

• 신호 어

  Danger

• 유해·위험 문구

  H300：삼키면 치명적임

  H310：피부와 접촉하면 치명적임

  H330：흡입하면 치명적임

  H400：수생생물에 매우 유독함

• 예방조치문구

  P260：분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.

  P262：눈, 피부, 의복에 묻지 않도록 하시오.

  P264：취급 후에는 손을 철저히 씻으시오.

  P264：취급 후에는 손을 철저히 씻으시오.

  P270：이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.

  P271：옥외 또는 환기가 잘 되는 곳에서만 취급하시오.

  P273：환경으로 배출하지 마시오.

  P280：보호장갑/보호의/보안경/안면보호구를 착용하시오.

  P284：호흡 보호구를 착용하시오.

  P301+P310：삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.

  P302+P350：피부에 묻은 경우,비눗물로 부드럽게 씻기

  P304+P340：흡입하면 신선한 공기가 있는 곳으로 옮기고 호흡하기 쉬운 자세로 안정을 취하시오.

  P310：즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.

  P320：긴급히 (…) 처치를 하시오.

  P321：(…) 처치를 하시오.

  P322：특정 조치(라벨의 … 참조)

  P330：입을 씻어내시오.

  P361：즉시 오염된 의복을 모두 벗을 것

  P363：다시 사용전 오염된 의류는 세척하시오.

  P391：누출물을 모으시오.

  P403+P233：용기는 환기가 잘 되는 곳에 단단히 밀폐하여 저장하시오.

  P405：밀봉하여 저장하시오.

  P501：...에 내용물 / 용기를 폐기 하시오.

나트륨 플루오로아세트산 화학적 특성, 용도, 생산

• 화학적 성질

  Sodium fluoroacetate is a fluffy, colorless, odorless, hygroscopic solid (sometimes dyed black).

• 용도

  Sodium fluoroacetate is used for rodent control in restricted environments and for the control of the brushtail possum and other wild mammals in some countries.

• 일반 설명

  A fine, white, odorless, powdered solid. Toxic by ingestion, inhalation and skin absorption. Used as a rodenticide.

• 공기와 물의 반응

  Water soluble.

• 반응 프로필

  Salts, basic, such as SODIUM FLUOROACETATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

• 위험도

  Toxic by ingestion, inhalation, and skin absorption. For use by trained operators only, use has been restricted. Cardiac impairment, central nervous system impairment, and nausea.

• 건강위험

  SODIUM FLUOROACETATE is super toxic. The probable oral lethal dose in humans is less than 5 mg/kg, or a taste (less than 7 drops) for a 150-lb. person.

• 화재위험

  When heated to decomposition, SODIUM FLUOROACETATE emits highly toxic fumes of sodium oxide and fluorides. Avoid decomposing heat.

• 농업용

  Insecticide, Rodenticide, Wildlife control: A U.S. EPA restricted Use Pesticide (RUP). Not listed for use in EU countries. It is seldom used as an insecticide. Sodium fluoroacetate is primarily used around sewers, ships and warehouses, and in agriculture and by state agricultural departments as bait for rodents and large predators, to control rats, mice, squirrels, prairie dogs, coyotes, rabbits and otherpests. It is seldom used as an insecticide. It is very toxic to birds, domestic animals and wildlife either by consuming the bait or eating poisoned carcasses. It is sometimes used in 1% solutions which are injected into collars which are strapped to the necks of sheep, goats and other livestock that predators are attracted to. Coyotes that puncture the collars are likely to be fatally poisoned by the sodium fluoroacetate as a result.

• 상품명

  AI3-08434®; FLUORAKIL® 3; FRATOL®; FURATOL®; RATBANE 1080®; TENEIGHTY®; TL 869®; YASOKNOCK®

• Safety Profile

  A deadly human poison by ingestion. Experimental poison by ingestion, skin contact, intraperitoneal, subcutaneous, and intravenous routes. A very highly toxic water-soluble salt used mainly as an immediate-action rodenticide. It is absorbed rapidly by the gastrointestinal tract but slowly by the skin unless the skin is abraded or cut. It operates by blocking the Krebs cycle by formation of fluorocitric acid, which inhbits aconitase. It has an effect on either the cardiovascular or nervous system, or both, in all species and, in some species, the skeletal muscles. Humans have mixed responses, with the cardiac feature predominating. By a duect action on the heart, contractile power is lost, which leads to declining blood pressure. Ventricular premature contractions and arrhythmias are seen in all species, including humans. The central nervous system is directly attacked by sodtum fluoroacetate. In humans, the action on the central nervous system produces epileptiform convulsive seizures followed by severe depression. The dangerous dose for humans is 0.5-2 mg/kg. Other species vary considerably in their response to hs material, with primates and birds being the most resistant and carnivora and rodents being the most susceptible. Most domestic animals show a susceptibility fahng between the two extremes indtcated above. Experimental reproductive effects. When heated to decomposition it emits highly toxic fumes of NazO and F-.

• 잠재적 노출

  A potential danger to those involved in the manufacture, formulation, and application of this highly toxic, immediate-action rodenticide.

• Carcinogenicity

  In developmental studies in rats 0.75mg/kg/day administered by gavage on days 6–17 of gestation caused significant reductions in maternal and fetal body weight gains, but no external fetal abnormalities were noted.

• 환경귀착

  Ingestion, inhalation, and dermal exposures are all possible, but ingestion is the major route of exposure. Sodium fluoroacetate is rapidly absorbed by the gastrointestinal tract and by the lungs. There is evidence that leaching and metabolism are the major routes of dissipation. Sodium fluoroacetate which has not undergone degradation is considered mobile by the EPA and has a high risk for movement into the soil and the ground water. Once adsorbed in soil, sodium fluoroacetate can be degraded by halidohydrolase in many microbial and fungal species. The ‘half-life’ of sodium fluoroacetate in soil is dependent on temperature, weather, and initial amount of chemical and decomposition of the host animal. There have been no reports that sodium fluoroacetate can leach into water and reach levels exceeding that which would be deemed toxic.

• 신진 대사 경로

  Sodium fluoroacetate is toxic to all mammals, especially to dogs (LD50 0.1 mg kg^-1) and therefore its use is very restricted. An exception is the aerial application of baits for the control of the brushtail possum in New Zealand and of other wild mammals in Australia. Such use is controversial and has been the impetus for some environmental fate studies (Eason et al., 1993) and secondary toxicity studies.
  The role of fluoroacetate in interfering with citrate metabolism is now classical biochemical toxicology (see below).

• 운송 방법

  UN2629 Sodium fluorosilicate, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

• Purification Methods

  It is a free-flowing white HIGHLY TOXIC powder which is purified by dissolving it in ca 4 parts of H2O and the pH is checked. If it is alkaline, add a few drops of FCH2CO2H to make the solution just acidic. Evaporate (fumehood) on a steam bath until crystals start to separate, cool and filter the solid off. More solid can be obtained by adding EtOH to the filtrate. Dry it at 100o in vacuum. The p-nitrobenzyl ester crystallises from EtOH with m 76o. POISONOUS. The free acid interferes with the citric acid cycle. [Saunders & Stacey J Chem Soc 1778 1948, Beilstein 2 IV 446.]

• 비 호환성

  Incompatible with alkaline metals and carbon disulfide. Avoid decomposing heat.

• 폐기물 처리

  Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. This compound is unstable at temperatures above 110°C and decomposes @ 200°C. Thus, careful incineration has been suggested as a disposal procedure. According to their procedure, the produce should be mixed with large amounts of vermiculite, sodium bicarbonate, and sand-soda ash. Slaked lime should also be added to the mixture. Two incineration procedures for this mixture are suggested. The better of these procedures is to burn the mixture in a closed incinerator equipped with an afterburner and an alkali scrubber. The other procedure suggests that the mixture be covered with scrap wood and paper in an open incinerator. (The incinerator should be lighted by means of an excelsior train).

나트륨 플루오로아세트산 준비 용품 및 원자재

나트륨 플루오로아세트산 관련 검색