사이클로산

한글명:사이클로산

카스 번호1134-23-2

상품명:CYCLOATE

CBNumberCB0134167

분자식C11H21NOS

포뮬러 무게215.36

MOL 파일1134-23-2.mol

동의어(한글)

사이클로산

사이클로산(CYCLOATE)

화학적 성질

녹는점	11.5°C
끓는 점	145 °C(Press: 10 Torr)
밀도	1.0156
증기압	0.002Pa at 25℃
굴절률	1.5500 (estimate)
인화점	>100 °C
저장 조건	0-6°C
물리적 상태	액체
산도 계수 (pKa)	-1.30±0.20(Predicted)
수용성	85mg/L(22℃)
BRN	2937178
주요 응용	agriculture environmental
InChI	1S/C11H21NOS/c1-3-12(11(13)14-4-2)10-8-6-5-7-9-10/h10H,3-9H2,1-2H3
InChIKey	DFCAFRGABIXSDS-UHFFFAOYSA-N
SMILES	CCSC(=O)N(CC)C1CCCCC1
LogP	3.88 at 20℃
CAS 데이터베이스	1134-23-2
EPA	Cycloate (1134-23-2)

위험 및 안전 성명

위험품 표기	Xn,N
위험 카페고리 넘버	22-51/53
안전지침서	61
유엔번호(UN No.)	UN3082 9/PG 3
WGK 독일	2
RTECS 번호	GU7200000
스토리지 클래스	6.1C - Combustible acute toxic Cat.3 toxic compounds or compounds which causing chronic effects
Hazard Classifications	Acute Tox. 3 Inhalation Aquatic Chronic 2
유해 물질 데이터	1134-23-2(Hazardous Substances Data)
독성	LC50 (96-hour) for rainbow trout 4.5 mg/L (Hartley and Kidd, 1987), for mosquito fish 10 ppm (Humburg et al., 1989); acute oral LD50 of technical cycloate for male and female rats 2,000–3,190 and 3,160–4,100 mg/kg, respectively (Hartley and Kidd, 1987), 1,678 mg/kg (RTECS, 1985)

그림문자(GHS)

사이클로산 화학적 특성, 용도, 생산

화학적 성질
Cycolate is an oily, clear, or amber to yellow liquid. Aromatic odor;
용도
Herbicide used to control several broad-leaved weeds and many annual grasses in sugar beets, table beets and spinach
일반 설명
Colorless liquid with an aromatic odor. Used as a selective systemic herbicide.
공기와 물의 반응
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids or alkalis.
반응 프로필
CYCLOATE is a thiocarbamate ester. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
농업용
Herbicide: Used to control broadleaf weeds, annual and perennial grasses and nutgrass in spinach, beets, and sugar beets. Not approved for use in EU countries. Actively registered in the U.S.
상품명
ETSAN®; EUREX®; R-2063®; RO- NEET®; RO-NEET®-6E; RO-NEET® 10G; RONIT®; SABET®
잠재적 노출
Cycolate is a thiocarbamate herbicide used to control broad leaf weeds, annual and perennial grasses and nutgrass in spinach, beets, and sugar beets.
환경귀착
Soil. The reported half-life in soil is approximately 4–8 weeks (Hartley and Kidd, 1987)
Groundwater. According to the U.S. EPA (1986) cycloate has a high potential to leach to groundwater
Plant. Cycloate is rapidly metabolized in sugarbeets to carbon dioxide, ethylcyclohexylamine, sugars, amino acids and other natural constituents (Humburg et al., 1989)
Chemical/Physical. In the gas phase, cycloate reacts with hydroxyl and NO3 radicals but not with ozone. With hydroxy radicals, cleavage of the cyclohexyl ring was suggested leading to the formation of a compound tentatively identified as C2H5(CHO)NC(O)SC2H5. The calculated photolysis lifetimes of cycloate in the troposphere with hydroxyl and NO3 radicals are 5.2 hours and 1.4 days, respectively (Kwok et al., 1992).
운송 방법
UN3082 Environmentally Hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz- ardous material, Technical Name Required
비 호환성
Cycolate reacts violently with powerful oxidizers such as calcium hypochlorite. Thiocarbamate esters are combustible. Poisonous gases are generated by the thermal decomposition of thiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitro- gen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solu- tion to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of thio- carbamates with aldehydes, nitrides, and hydrides. Thiocarbamates are incompatible with acids, peroxides, and acid halides.
폐기물 처리
Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guid- ance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

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