1,5-ジアミノナフタレン

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H351：発がんのおそれの疑い

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P202：全ての安全注意を読み理解するまで取り扱わないこ と。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

  P391：漏出物を回収すること。

  P405：施錠して保管すること。

1,5-ジアミノナフタレン 価格

MSDS Information

• 1,5-Diaminonaphthalene

1,5-ジアミノナフタレン 化学特性,用途語,生産方法

• 外観

  白色～紫褐色, 結晶～粉末

• 溶解性

  水に難溶 (0.38g/L), 熱水に可溶。エタノール, エーテルに可溶。アセトンに溶ける。

• 用途

  試薬、工業用原料

• 用途

  有機合成原料。

• 使用上の注意

  不活性ガス封入

• 化学的特性

  GREY TO DARK BROWN POWDER. 1,5-Naphthalenediamine [2243-62-1]. 1,5-diaminonaphthalene, Alphamin, C10H10N2, Mr 158.2: oxidation of 97 with iron (III) chloride in water produces a blue-violet color. Treatment with boiling aqueous sodium bisulfite followed by addition of alkali gives a mixture of 1-amino-5-hydroxynaphthalene and 1,5-dihydroxynaphthalene. Sulfonation (5 % oleum, 100℃) gives 1,5-diaminonaphthalene2-sulfonic acid, and nitration in acetic acid produces 2,4,6,8-tetranitro-1,5-diaminonaphthalene. Coupling with diazo compounds takes place in the 2-position; reduction of the resulting azo compound with SnCl2– HCl produces 1,2,5- triaminonaphthalene.

• 使用

  1,5-naphthalenediamine be used as intermediates for the synthesis of materials.

• 調製方法

  1-Nitronaphthalene can be nitrated further to give a 40 : 60 mixture of 1,5- and 1,8-dinitronaphthalenes. Similar results are obtained by direct nitration of naphthalene with H2SO4– HNO3 under careful control of temperature over the range 40 – 80℃. Although separation of the isomers by fractional crystallization or solvent extraction is usually carried out at this stage, the mixed isomers can also be reduced and the resulting diamines separated. Reduction of the dinitronaphthalenes is achieved by treatment of a nonaqueous solution with iron or hydrogen in the presence of a catalyst. An alternative process for 1,5-naphthalenediamine involves amination of 1,5-dihydroxynaphthalene with ammonia and ammonium bisulfite. Although less efficient on a stage basis it offers an economical alternative to nitration and reduction if the 1,8-naphthalenediamine is not also required.
  

• 定義

  ChEBI: A naphthalenediamine compound having amino substituents in the 1- and 5-positions.

• 一般的な説明

  Colorless to pale purple crystals or lavender powder.

• 空気と水の反応

  1,5-Naphthalenediamine is sensitive to prolonged exposure to air. Insoluble in water.

• 反応プロフィール

  1,5-Naphthalenediamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

• 危険性

  Questionable carcinogen.

• 火災危険

  Flash point data for 1,5-Naphthalenediamine are not available. 1,5-Naphthalenediamine is probably combustible.

• 安全性プロファイル

  Suspected carcinogen with experimental carcinogenic, neoplastigenic, tumorigenic data. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.

• 純化方法

  Recrystallise the amino-naphthalene from boiling H2O, but this is wasteful due to poor solubility. Boil it in chlorobenzene (charcoal), filter hot and cool the filtrate (preferably under N2). This gives colourless crystals. Dry it in a vacuum till free from chlorobenzene (odour), and store it in sealed ampoules under N2 away from light. [Beilstein 13 IV 340.]

1,5-ジアミノナフタレン 上流と下流の製品情報

1,5-ジアミノナフタレン 生産企業

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1,5-ジアミノナフタレン スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

2243-62-1, 1,5-ジアミノナフタレン キーワード