酢酸メチル

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H225：引火性の高い液体および蒸気

  H319：強い眼刺激

  H336：眠気やめまいのおそれ

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P233：容器を密閉しておくこと。

  P240：容器を接地すること/アースをとること。

  P241：防爆型の電気機器/換気装置/照明機器/．．．機器を使 用すること。

  P242：火花を発生させない工具を使用すること。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

酢酸メチル 価格

酢酸メチル 化学特性,用途語,生産方法

• 外観

  無色澄明の液体

• 定義

  本品は、酢酸とメタノールのエステルであり、次の化学式で表される。

• 溶解性

  エタノール及びジエチルエーテルに極めて溶けやすく、水に溶けやすい。

• 解説

  酢酸メチル メタノールと酢酸とを硫酸触媒の存在下で加熱すると得られる．果実の芳香をもつ無色の液体．融点－98 ℃，沸点56.9 ℃．0.9342．1.3614．引火点－10 ℃．水に可溶．エタノール（エチルアルコール）、エーテルなどの有機溶媒と任意の割合で混じり合うほか、水にもかなり溶ける。合成樹脂、ペイント、香料などの溶剤としての用途をもつ。

• 用途

  環境ホルモン物質であるアルキルフェノール類およびビスフェノールAを分析する際に、抽出溶媒として用いられます。

• 用途

  合成反応用溶剤、塗料?印刷インキ用溶剤、マニキュア、ラッカー、香料の溶剤

• 用途

  溶剤（香料、ニトロセルロース、合成樹脂、塗料他）

• 用途

  溶剤。

• 化粧品の成分用途

  溶剤、香料

• 主な用途

  ソルベントMEは酢酸メチル約80%とメタノール約20%の混合溶剤です。主に塗料用溶剤や洗缶用溶剤として使用されています。

• 説明

  Methyl acetate, also known as MeOAc , acetic acid methyl ester or methyl ethanoate, is a carboxylate ester with the formula CH3COOCH3. It is a flammable liquid with a characteristically pleasant smell reminiscent of some glues and nail polish removers. Methyl acetate is occasionally used as a solvent, being weakly polar and lipophilic, but its close relative ethyl acetate is a more common solvent being less toxic and less soluble in water. Methyl acetate has a solubility of 25% in water at room temperature. At elevated temperature its solubility in water is much higher. Methyl acetate is not stable in the presence of strong aqueous bases or aqueous acids. Methyl acetate is VOC exempt.

• 化学的特性

  Methyl acetate has a pleasant, fruity odor and slightly bitter flavor. May be prepared by boiling acetic acid and methanol in the presence of acid catalysts; or by heating methanol with an excess carbon monoxide under pressure in the presence of a catalyst (phosphoric acid, cobalt salts).
  Methyl acetate occurs naturally in low concentrations in mint, fungus,grapes, banana, coffee (Furia and Bellanca, 1975) and is a volatile constituent of nectarines (Takeoka et al., 1988). It is also present in some distilled alcoholic beverages (Shimoda et al., 1993). It is produced industrially via the carbonylation of methanol as a byproduct of acetic acid production or by esterification of acetic acid with methanol in the presence of strong acid such as sulfuric acid.

• 物理的性質

  Colorless liquid with a pleasant odor. An odor threshold concentration of 48 ppb_v was reported by Nagata and Takeuchi (1990). Cometto-Mu?iz and Cain (1991) reported an average nasal pungency threshold concentration of 112,500 ppm_v.

• 天然物の起源

  Reported found in apple, banana, sweet and sour cherry, tangerine juice, black currants, guava, grapes, melon, peach, pear, pineapple, strawberry, cabbage, tomato, clove bud, peppermint oil, vinegar, bread, cheeses, butter, yogurt, beef, beer, cognac, rum, whiskies, cider, sherry, grape wines, cocoa, coffee, filbert, peanut, honey, soybean, olive, passion fruit, fruit brandies, fig, gin, kiwifruit, clary sage, arrack and nectarine.

• 使用

  Methyl acetate is used as a solvent forlacquers, resins, oils, and nitrocellulose; inpaint removers; as a flavoring agent; and inthe manufacture of artificial leather.

• 製造方法

  Methyl acetate is produced industrially via the carbonylation of methanol as a byproduct of the production of acetic acid.Methyl acetate also arises by esterification of acetic acid with methanol in the presence of strong acids such as sulfuric acid, this production process is famous because of Eastman Kodak's intensified process using a reactive distillation.
  2–1-Reactions
  In the presence of strong bases such as sodium hydroxide or strong acids such as hydrochloric acid or sulfuric acid it is hydrolyzed back into methanol and acetic acid, especially at elevated temperature. The conversion of methyl acetate back into its components, by an acid , is a first-order reaction with respect to the ester. The reaction of methyl acetate and a base, for example sodium hydroxide, is a second-order reaction with respect to both reactants.
  3-Applications
  A major use of methyl acetate is as a volatile low toxicity solvent in glues, paints, and nail polish removers. Acetic anhydride is produced by carbonylation of methyl acetate in a process that was inspired by the Monsanto acetic acid synthesis.

• 主な応用

  Methyl acetate may be used for the preparation of fatty acid methyl esters and triacetin from rapeseed oil via non-catalytic trans-esterification reaction under super-critical conditions.
  Methyl acetate may be used in the following:
  As acyl acceptor in the preparation of biodiesel.
  Synthesis of ethanol.
  Preparation of n-butyl acetate, via transesterification reaction with n-butanol in the presence of acidic catalysts.
  It may also be used as a precursor in the synthesis of the following:
  acetic anhydride
  methyl acrylate
  vinyl acetate
  ethyl amide

• 定義

  ChEBI: Methyl acetate is an acetate ester resulting from the formal condensation of acetic acid with methanol. A low-boiling (57°C) colourless, flammable liquid, it is used as a solvent for many resins and oils. It has a role as a polar aprotic solvent, a fragrance and an EC 3.4.19.3 (pyroglutamyl-peptidase I) inhibitor. It is an acetate ester, a methyl ester and a volatile organic compound.

• 一般的な説明

  Methyl acetate appears as a clear colorless liquid with a fragrant odor. Moderately toxic. Flash point 14 °F. Vapors heavier than air.

• 空気と水の反応

  Highly flammable. Water soluble.

• 反応プロフィール

  Methyl acetate presents a fire or explosion hazard when exposed to strong oxidizing agents. Emits irritating fumes and acrid smoke when heated to decomposition, [Lewis, 3rd ed., 1993, p. 826]. Methyl acetate reactivity is consistent with other compounds of the ester group.

• 危険性

  Flammable, dangerous fire and explosion risk, explosive limits in air 3–16%. Irritant to respiratory tract. Headache, dizziness, nausea, eye damage (degeneration of ganglion cells in the retina).

• 健康ハザード

  (Very similar to those of methyl alcohol, which constitutes 20% of commercial grade.) Inhalation causes headache, fatigue, and drowsiness; high concentrations can produce central nervous system depression and optic nerve damage. Liquid irritates eyes and may cause defatting and cracking of skin. Ingestion causes headache, dizziness, drowsiness, fatigue; may cause severe eye damage.

• 火災危険

  Behavior in Fire: Vapor is heavier than air and may travel a considerable distance to a source of ignition and flash back.

• 安全性プロファイル

  Moderately toxic by several routes. A human systemic irritant by inhalation. A moderate skin and eye irritant. Mutation data reported. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderate explosion hazard when exposed to heat or flame. When heated to decomposition it emits acrid smoke and fumes. See also ESTERS.

• 職業ばく露

  Methyl acetate is used as a solvent in lacquers and paint removers; and as an intermediate in pharmaceutical manufacture.

• 環境運命予測

  Photolytic. A rate constant of 2.00 x 10^-13 cm³/molecule?sec was reported for the reaction of methyl acetate and OH radicals in aqueous solution (Wallington et al., 1988b).
  Chemical/Physical. Slowly hydrolyzes in water yielding methyl alcohol and acetic acid (NIOSH, 1997). The estimated hydrolysis half-life in water at 25 °C and pH 7 is 2.5 yr (Mabey and Mill, 1978).
  At an influent concentration of 1,030 mg/L, treatment with GAC resulted in an effluent concentration of 760 mg/L. The adsorbability of the carbon used was 54 mg/g carbon (Guisti et al., 1974).

• 輸送方法

  UN1231 Methyl acetate, Hazard Class: 3; Labels: 3-Flammable liquid.

• 純化方法

  Methanol in methyl acetate can be detected by measuring its solubility in water. At 20o, the solubility of methyl acetate in water is ca 35g per 100mL, but 1% MeOH confers complete miscibility. Methanol can be removed by conversion to methyl acetate, by refluxing for 6hours with acetic anhydride (85mL/L), followed by fractional distillation. Acidic impurities can be removed by shaking with anhydrous K2CO3 and distilling. An alternative treatment is with acetyl chloride, followed by washing with concentrated NaCl and drying with CaO or MgSO4. (Solid CaCl2 cannot be used because it forms a crystalline addition compound.) Distillation from copper stearate destroys peroxides. Free alcohol or acid can be eliminated from methyl acetate by shaking with strong aqueous Na2CO3 or K2CO3 (three times), then with aqueous 50% CaCl2 (three times), saturated aqueous NaCl (twice), drying with K2CO3 and distilling it from P2O5. [Beilstein 2 IV 122.]

• 不和合性

  Vapor may form explosive mixture with air. A Strong reducing agent. Incompatible water, acids, nitrates, strong oxidizers; alkalis. Attacks some plastics. Attacks many metals in presence of water. Reacts slowly with water, forming acetic acid and methanol. Decomposes in heat; on contact with air, bases, strong oxidizers; UV-light; possible fire and explosion hazard

• 廃棄物の処理

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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