ヨウ化エチル

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H226：引火性の液体および蒸気

  H302：飲み込むと有害

  H315：皮膚刺激

  H317：アレルギー性皮膚反応を起こすおそれ

  H319：強い眼刺激

  H334：吸入するとアレルギー、喘息または、呼吸困難 を起こすおそれ

  H335：呼吸器への刺激のおそれ

  H341：遺伝性疾患のおそれの疑い

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P312：飲み込んだ場合：気分が悪い時は医師に連絡する こと。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

ヨウ化エチル 価格

ヨウ化エチル 化学特性,用途語,生産方法

• 外観

  無色～暗褐色, 澄明の液体

• 溶解性

  エタノール及びアセトンに極めて溶けやすく、水に溶けにくい。

• 解説

  ヨウ化エチル，液体．融点－110.9 ℃，沸点72.3 ℃．d¹⁵₄ 1.9470．n¹⁵_D"1.5168．水に難溶，有機溶媒に易溶．エチル化剤として用いられる．

  森北出版「化学辞典（第2版）
  

• 用途

  調査用途のみ。 臨床及び体外診断には使用できません。

• 用途

  有機合成原料。

• 製造

  ヨードエタンともいう．エタノールにヨウ素と赤リンを作用させるか，硫酸ジエチルにヨウ化カリウム水溶液を作用させてつくるヨウ化エチル．

• 化学的特性

  Colorless to yellow liquid. Iodoethane is a stable chemical substance. It is incompatible with strong bases, magnesium, and strong oxidising agents and gets discoloured when exposed to light, moisture, and air.

• 使用

  Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

• 定義

  ChEBI: An iodoalkane that is ethane substituted by an iodo group.

• 一般的な説明

  Iodoethane also known as ethyl iodide is an alkyl iodide. The interaction of iodoethane with Pt(111) surfaces has been analyzed by using thermal desorption and X-ray photoelectron spectroscopy. Its microwave spectrum has been recorded and studied. The dynamics of the gas phase photolysis of iodoethane have been studied using resonance Raman spectra. Its thermodynamic characteristics in the ideal state have been reported.

• 危険性

  Toxic by inhalation and skin absorption, narcotic in high concentration.

• 合成方法

  乾燥したエタノールにヨウ素とリンを作用させて製造される

• 純化方法

  Drying the iodide with P2O5 is unsatisfactory, and with CaCl2 it is incomplete. It is probably best to dry it with sodium wire and distil [Hammond et al. J Am Chem Soc 82 704 1960]. Exposure of ethyl iodide to light leads to rapid decomposition, with the liberation of iodine. Free iodine can be removed by shaking with several portions of dilute aqueous Na2S2O3 (until the colour is discharged), followed by washing with water, drying (with CaCl2, then sodium), and distilling. The distilled ethyl iodide is stored, over mercury, in a dark bottle away from direct sunlight. Other purification procedures include passage through a 60cm column of silica gel, followed by distillation, and treatment with elemental bromine, extraction of free halogen with Na2S2O3 solution, followed by washing with water, drying and distilling. Free iodine and HI have also been removed by direct distillation through a LeBel-Henninger column containing copper turnings. Purification by shaking with alkaline solutions, and storage over silver, are reported to be unsatisfactory. [Beilstein 1 IV 163.]

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ヨウ化エチル スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS)

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