3-メチル-1-ブチン-3-オール

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H225：引火性の高い液体および蒸気

  H302：飲み込むと有害

  H318：重篤な眼の損傷

  H336：眠気やめまいのおそれ

• 注意書き

  P202：全ての安全注意を読み理解するまで取り扱わないこ と。

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P312：飲み込んだ場合：気分が悪い時は医師に連絡する こと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

3-メチル-1-ブチン-3-オール 価格

MSDS Information

• 2-Methylbut-3-yn-2-ol

3-メチル-1-ブチン-3-オール 化学特性,用途語,生産方法

• 外観

  無色～うすい黄色, 澄明の液体

• 溶解性

  水, エタノールに混和。水、エタノール及びアセトンに極めて溶けやすい。

• 用途

  有機合成原料。

• 用途

  テルペン香料,香料,合成樹脂などの中間体,粘度安定剤,減粘剤,金属の防食剤

• 化学的特性

  colourless to light yellow liquid.
  Methylbutynol (3-Methyl butynol) is a colorless, transparent, and aromatic liquid that can be consumed at room temperature. It is soluble in water and fatty acids and miscible with acetone, benzene, carbon tetrachloride, and petroleum ether but insoluble in ammonia. Methylbutynol and water form an azeotrope with an azeotropic point of 91 °C in the methylbutynol composition of 74% and the water composition of 26%. Methylbutynol is chemically active and has the common reactions of alcohol groups and unsaturated triple bonds, such as addition, polymerization, esterification, and oxidation reactions.

• 使用

  Stabilizer in chlorinated solvents, viscosity reducer and stabilizer, electroplating brightener, intermediate.

• 一般的な説明

  Colorless to straw yellow liquid.

• 空気と水の反応

  Highly flammable.

• 反応プロフィール

  3-Methyl butynol is an alcohol. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

• 危険性

  Flammable, dangerous fire risk.

• 健康ハザード

  Contact will cause eye and skin irritation. Vapor exposure may cause eye and respiratory tract irritation.

• 火災危険

  Special Hazards of Combustion Products: Irritating and toxic gases, such as carbon dioxide and carbon monoxide, may be produced in fire.

• 合成

  Three parts of the strong basic anion exchange resin Amberlite IRA400 were suspended in 30 parts of 7% sodium hydroxide solution to change to OH type. After washing to neutral with water, the resin was suspended in methanol, and after 15–60 min, methanol was discharged. The treatment with methanol was repeated as described above until the water content of the effluent methanol was less than 0.1% and the water content of the ion exchange resin was less than 0.2%. The tubular reactor was filled with the ion exchange resin, and then acetone was saturated with acetylene, and liquid ammonia was introduced into the reactor at 2.5 MPa and 40 °C. Excess acetylene in reactants was used to reduce the side reaction of acetone. After ethynylation, the reaction solution was subjected to a flash evaporation at 50 °C. The remaining solution was distilled to obtain methylbutynol (3-methyl butynol).
  

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3-メチル-1-ブチン-3-オール スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS、Raman)

115-19-5, 3-メチル-1-ブチン-3-オール キーワード