1,1,2-トリフルオロトリクロロエタン

化学名:1,1,2-トリフルオロトリクロロエタン

CAS番号.76-13-1

英語名:1,1,2-Trichlorotrifluoroethane

CBNumberCB8738958

MFC2Cl3F3

MW187.38

MOL File76-13-1.mol

别名

1,1,2-トリフルオロ-1,2,2-トリクロロエタン

イスセオン113

フレオン113TR-T

1,1,2-トリフルオロトリクロロエタン物理性質

融点	−35 °C(lit.)
沸点	47-48 °C(lit.)
比重(密度)	1.57 g/mL at 25 °C(lit.)
蒸気密度	6.5 (vs air)
蒸気圧	5.5 psi ( 20 °C)
屈折率	n20/D 1.358(lit.)
闪点	195°C
貯蔵温度	2-8°C
溶解性	0.17g/リットル
外見	無色のガス;揮発性の液体。
水溶解度	0.02 g/100 mL。微溶性
BRN	1740335
Henry's Law Constant	0.154, 0.215, 0.245, 0.319, and 0.321 at 10, 15, 20, 25, and 30 °C, respectively (EPICS, Ashworth et al., 1988)
暴露限界値	TLV-TWA 1000 ppm (～7600 mg/m³) (ACGIH, MSHA, and OSHA); TLV-STEL 1250 ppm (ACGIH).
Dielectric constant	2.6（21℃）
安定性：	安定。不燃性。アルカリ金属、反応性金属、マグネシウム、亜鉛、アルミニウムとは混和しません。
LogP	3.160
CAS データベース	76-13-1(CAS DataBase Reference)
NISTの化学物質情報	Ethane, 1,1,2-trichloro-1,2,2-trifluoro-(76-13-1)
EPAの化学物質情報	CFC-113 (76-13-1)

安全性情報

主な危険性	N,Xi,T,F
Rフレーズ	52/53-59-39/23/24/25-23/24/25-51/53-11
Sフレーズ	59-61-45-36/37-16
RIDADR	UN 3082 9/PG 3
WGK Germany	2
RTECS 番号	KJ4000000
自然発火温度	1256 °F
Hazard Note	Irritant
有毒物質データの	76-13-1(Hazardous Substances Data)
毒性	Acute oral LD50 for rats 43 mg/kg (quoted, RTECS, 1985).
IDLA	2,000 ppm
化審法	一般化学物質
PRTR法	第1種指定化学物質
環境リスク評価	1,1,2-トリクロロ-1,2,2-トリフルオロエタン(76-13-1)

危険有害性情報のコード(GHS)

1,1,2-トリフルオロトリクロロエタン価格

製品番号	包装	価格	製品説明	購入
Sigma-Aldrich Japan 4S7944	1mL	￥10100	analytical standard, 2000?μg/mL in methanol	購入
Sigma-Aldrich Japan 48411	1mL	￥5000	certified reference material, 1000?μg/mL in methanol	購入
Sigma-Aldrich Japan 48411	48411	￥17600	certified reference material, 1000?μg/mL in methanol	購入
Sigma-Aldrich Japan 4S7944	4s7944	￥19100	analytical standard, 2000?μg/mL in methanol	購入

1,1,2-トリフルオロトリクロロエタン化学特性,用途語,生産方法

用途
製造用剤
化学的特性
colourless liquid or gas
物理的性質
Clear, colorless liquid with a carbon tetrachloride-like odor at high concentrations
使用
Dry-cleaning solvent, fire extinguishers, to make chlorotrifluoroethylene, blowing agent, polymer intermediate, solvent drying, drying electronic parts and precision equipment.
一般的な説明
Colorless liquid with a sweet, ether-like odor. Sinks in water.
空気と水の反応
Insoluble in water.
反応プロフィール
1,1,2-Trichlorotrifluoroethane yields violent reactions with Al, Ba, Li, Sm, Na/K alloy and Ti . May react exothermically with aluminum.
健康ハザード
Inhalation causes irritation of the nose, throat, and lungs. High concentrations may cause death by respiratory failure or asphyxiation. May produce superficial skin burns or defatting type dermatitis and may irritate the eyes.
火災危険
Noncombustible liquid.
工業用途
1,1,2-Trichlorotrifluoroethane (CFC 113) is generally a stable molecule not prone to the reactivity that is often shown by the chlorinated hydrocarbons. The solvent blends that contain the fluorinated hydrocarbon and an alcohol display some metal reactivity which is inhibited by adding nitromethane as a stabilizer.
安全性プロファイル
Mildly toxic by ingestion and inhalation. Affects the central nervous system in humans. A sktn irritant. Combustible when exposed to heat or flame. Incompatible with Al, Ba, Li, Sm, NaK alloy, Ti. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and FLUORIDES.
職業ばく露
TTE is used as a solvent and refrigerant; it is used in fire extinguishers; as a blowing agent and as an intermediate in the production of chlorotrifluoroethylene monomer by reaction with zinc.
発がん性
A 2 year inhalation toxicity study/carcinogenicity study was conducted by Trochimowicz et al. in which groups of 100 male and 100 female rats were exposed to levels of up to of 20,000 ppm of CFC 113 6 h/day, 5 days/week for 2 years. Although five nasal tumors were seen, one at 20,000 ppm and four at 10,000 ppm, all five were different morphological types and were judged not to be exposure related. In addition, there was a small increase (5.8%) in pancreatic islet cell adenomas in the females exposed to 20,000 ppm; however, this was within the normal control range.
In a second study, injection of 0.1mLof 10% CFC 113 was not carcinogenic. But when given with a 5% solution of piperonyl butoxide, hepatomas were induced in male mice. The significance of this experimental finding has never been determined.
環境運命予測
Biological. In an anoxic aquifer beneath a landfill in Ottawa, Ontario, Canada, there was evidence to suggest that 1,1,2-trichlorotrifluoroethane underwent reductive dehalogenation to give 1,2-difluoro-1,1,2-trichloroethylene and 1,2-dichloro-1,1,2-trifluoroethane. It was proposed that the latter compound was degraded via dehydrodehalogenation to give 1-chloro-1,1,2-trifluoroethylene (Lesage et al., 1990).
Chemical/Physical. 1,1,2-Trichlorotrifluoroethane will not hydrolyze to any reasonable extent (Kollig, 1993).
輸送方法
UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
純化方法
Wash it with water, then with weak alkali. Dry it with CaCl2 or H2SO4 and distil it. [Locke et al. J Am Chem Soc 56 1726 1934, Beilstein 1 III 157, 1 IV 142.]
不和合性
Violent reaction with chemically active metals (such as powdered aluminum; beryllium, magnesium and zinc); calcium. Contact with alloys containing more than 2% magnesium causes decomposition, releasing hydrogen chloride, hydrogen fluoride; and carbon monoxide. May react exothermically with aluminum.
廃棄物の処理
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced.

1,1,2-トリフルオロトリクロロエタン上流と下流の製品情報

1,1,2-トリフルオロトリクロロエタン生産企業

1,1,2-トリフルオロトリクロロエタンスペクトルデータ(¹³CNMR、IR1、MS、Raman)

76-13-1, 1,1,2-トリフルオロトリクロロエタンキーワード

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1,1,2-トリフルオロトリクロロエタン

危険有害性情報のコード(GHS)

1,1,2-トリフルオロトリクロロエタン 価格

1,1,2-トリフルオロトリクロロエタン 化学特性,用途語,生産方法

1,1,2-トリフルオロトリクロロエタン 上流と下流の製品情報

1,1,2-トリフルオロトリクロロエタン 生産企業

1,1,2-トリフルオロトリクロロエタン スペクトルデータ(13CNMR、IR1、MS、Raman)

76-13-1, 1,1,2-トリフルオロトリクロロエタン キーワード

1,1,2-トリフルオロトリクロロエタン価格

1,1,2-トリフルオロトリクロロエタン化学特性,用途語,生産方法

1,1,2-トリフルオロトリクロロエタン上流と下流の製品情報

1,1,2-トリフルオロトリクロロエタン生産企業

1,1,2-トリフルオロトリクロロエタンスペクトルデータ(¹³CNMR、IR1、MS、Raman)

76-13-1, 1,1,2-トリフルオロトリクロロエタンキーワード