4-アリル-1,2-ジメトキシベンゼン

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H302：飲み込むと有害

  H341：遺伝性疾患のおそれの疑い

  H351：発がんのおそれの疑い

  H411：長期的影響により水生生物に毒性

• 注意書き

  P201：使用前に取扱説明書を入手すること。

  P273：環境への放出を避けること。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

4-アリル-1,2-ジメトキシベンゼン 価格

MSDS Information

• Methyl eugenol

4-アリル-1,2-ジメトキシベンゼン 化学特性,用途語,生産方法

• 外観

  無色～わずかにうすい黄色, 澄明の液体

• 定義

  本品は、次の化学式で表される芳香族化合物である。

• 溶解性

  水に不溶 ＜0.1 g/100 mL at 19℃。

• 用途

  有機合成原料。

• 化粧品の成分用途

  香料

• 化学的特性

  colourless to light yellow liquid

• 天然物の起源

  Reported in the essential oils of Myrtaceae and Luraceae; it was identifed originally in the essential oil from roots of Asarum europaeum L and Asarum canadense L Subsequently, it was identifed as the main constituent of the oil from wood of Dacrydium franklinii Hook (97 5%), in Melaleuca bracteata F v M (leaves, 90 to 95%), in Cinnamomum oliveri Bail (leaves, 90 to 95%), and as a minor constituent in the oils of betel, citronella, Japanese calamus, pimenta, hyacinth, rose, basil, bay, cajeput and others Reported found in heated blackberry, pepper, lovage seed, chervil, lemon balm, alpinia species, clove buds, nutmeg, pepper, mace, tarragon, Ocimum sanctum, laurel, myrtle leaf and berry, rosemary, pimento berry and mastic gum leaf oil

• 使用

  Methyl eugenol may be used as an analytical reference standard for the quantification of the analyte in the following:????????
  
  • Essential oil of Pimenta pseudocaryophyllus using high-performance liquid chromatography (HPLC). The purity of the extracted compound is then determined by gas chromatography coupled to flame ionization detector (GC/FID).???????
  • Stem bark of Cinnamomum zeylanicum Blume using reversed-phase high-performance liquid chromatography (RP-HPLC) with UV-visible detection.???????
  • Rosa hybrida using gas-chromatography coupled to mass spectrometry (GC-MS) technique.
  
  

• 製造方法

  Usually prepared by methylation of eugenol.

• 一般的な説明

  Clear colorless to pale yellow liquid with a spicy earthy odor. Bitter burning taste.

• 空気と水の反応

  Insoluble in water.

• 反応プロフィール

  Methyl eugenol is incompatible with strong oxidizers . May react exothermically with reducing agents to release hydrogen gas.

• 危険性

  Possible carcinogen.

• 火災危険

  Methyl eugenol is combustible.

• 安全性プロファイル

  Confirmed carcinogen. Poison by intravenous route. Moderately toxic by ingestion and intraperitoneal routes. A skin irritant. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. Some other alkenylbenzenes have carcinogenic activity. See also EUGENOL, ALLYL COMPOUNDS, and ETHERS

• 職業ばく露

  Methyl eugenol is a naturally occurring substance found in the essential oils of several plant species. Methyleugenol is used as a flavoring agent in jellies, baked goods, nonalcoholic beverages, chewing gum, candy, pudding, relish, and ice cream. Methyleugenol has been used as an anesthetic in rodents. It also is used as an insect attractant in combination with insecticides.

• 発がん性

  Methyleugenol is reasonably anticipated to be a human carcinogenbased on sufficient evidence of carcinogenicity from studies in experimental animals.

• Solubility in organics

  Soluble in alcohol and oils

• 輸送方法

  UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

• 純化方法

  Recrystallise the ether from hexane at low temperature and redistil it (preferably in vacuo). [Hillmer & Schorning Z Phys Chem [A] 167 407 1934, Briner & Fliszár Helv Chim Acta 42 2063 1959, Beilstein 6 H 963, 6 IV 6337.]

• 不和合性

  Methyleugenol is Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Contact with reducing agents may cause the release of hydrogen gas

• 廃棄物の処理

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

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