五塩化イリジウム(IV)ジアンモニウム

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 注意書き

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P312：飲み込んだ場合：気分が悪い時は医師に連絡する こと。

五塩化イリジウム(IV)ジアンモニウム 価格

五塩化イリジウム(IV)ジアンモニウム 化学特性,用途語,生産方法

• 外観

  褐色～黒色, 結晶～粉末

• 溶解性

  水に溶ける。

• 用途

  触媒。

• 化学的特性

  Olive Green Crystals

• 使用

  Ammonium Hexachloroiridate(IV) is a reagent used for research applications and is used for catalytic production on hydrogen.
  It is a key intermediate in the isolation of iridium from ores. Most other metals form insoluble sulfides when aqueous solutions of their chlorides are treated with hydrogen sulfide, but [IrCl6]2? resists ligand substitution. Upon heating under hydrogen, the solid salt converts to the metal:
  (NH4)2[IrCl6] + 2 H2→ Ir + 6 HCl + 2 NH3

• 純化方法

  It is precipitated several times from aqueous solution by saturation with ammonium chloride. This removes any palladium and rhodium. It is then washed with ice-cold water and dried over conc H2SO4 in a vacuum desiccator. If osmium or ruthenium is present, it can be removed as the tetroxide by heating with conc HNO3, followed by conc HClO4, until most of the acid has been driven off. (This treatment is repeated. ) The near-dry residue is dissolved in a small amount of water and added to excess NaHCO3 solution and bromine water. On boiling, iridic (but not platinic) hydroxide is precipitated. It is dissolved in HCl and precipitated several times, then dissolved in HBr and treated with HNO3 and HCl to convert the bromides to chlorides. Saturation with ammonium chloride and cooling precipitates ammonium hexachloroiridate which is filtered off and purified as above [Woo & Yost J Am Chem Soc 53 884 1931].

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