二酢酸亜鉛

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H302：飲み込むと有害

  H318：重篤な眼の損傷

  H411：長期的影響により水生生物に毒性

• 注意書き

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P270：この製品を使用する時に、飲食または喫煙をしないこ と。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P312：飲み込んだ場合：気分が悪い時は医師に連絡する こと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

二酢酸亜鉛 価格

MSDS Information

• Zinc acetate

二酢酸亜鉛 化学特性,用途語,生産方法

• 外観

  無色澄明の液体

• 定義

  本品は、酢酸(*)の亜鉛塩であり、次の化学式で表される。
  参照表示名称：酢酸

• 溶解性

  水にやや溶けやすく、エタノールにやや溶けにくい。

• 用途

  亜鉛酢酸塩は化学式ZnCH3COO2で表される無機化合物ですこの化合物は亜鉛イオンと酢酸イオンから構成されており主に透明な結晶体または白色の粉末として存在します水やアルコールに容易に溶解し多くの化学反応において重要な役割を果たします

• 化粧品の成分用途

  皮膚保護剤、殺菌剤、収れん剤

• 説明

  Zinc acetate (chemical formula: Zn(O2CCH3)2) is a kind of salt commonly existing in the dihydrate form. It appears as colorless solid. It is produced through the reaction between zinc oxide with acetate acid. Given that zinc is an essential element for growth and development of human body, zinc acetate can be used as a dietary supplement for the treatment of zinc deficiency. It plays an important role for the synthesis of cholesterol, protein, and fats. It can also be used as an astringent, styptic and emetic. In industry, it has various kinds of applications including wood preservation, manufacturing of other zinc salts as well as ethylene acetate, being used as a dye mordant, and analytical reagent.

• 化学的特性

  Zinc acetate occurs as white crystalline, lustrous plates with a faint acetic odor and an astringent taste.

• 物理的性質

  The acetate group is capable of binding to metal ions in a variety of ways through its two oxygen atoms and several connectivities are observed for the various hydrates of zinc acetate. Anhydrous zinc acetate adopts a polymeric structure consisting of zinc coordinated to four oxygen atoms in a tetrahedral environment, each tetrahedron being connected to neighbors by the acetate groups . The acetate ligands are not bidentate. In contrast, most metal diacetates feature metals in octahedral coordination with bidentate acetate groups. In zinc acetate dihydrate the zinc is octahedral, wherein both acetate groups are bidentate.
  2 - 5 - Heating pad
  Heating Zn(CH3CO2)2 in a vacuum results in loss of acetic anhydride, leaving a residue of ""basic zinc acetate,"" with the formula Zn4O(CH3CO2)6. This cluster compound has the tetrahedral structure shown below. This species closely resembles the corresponding beryllium compound, although it is slightly expanded with Zn-O distances ～1.97 vs ～1.63 Å for Be4O(OAc)6.

• 製造方法

  Zinc acetate is prepared by the reaction of acetic acid with zinc oxide followed by crystallization (crystals of dihydrate obtained): ZnO + 2CH₃COOH → (CH₃COO)₂Zn + H₂O.

• 定義

  ChEBI: Zinc acetate is an acetate salt in which the cationic component is zinc(2+). It has a role as an astringent. It is a zinc molecular entity and an acetate salt.

• 調製方法

  Zinc acetate is synthesized by reacting zinc oxide with glacial acetic acid, with subsequent crystallization, separation by centrifugation, and drying and milling of the crystals. No organic solvents are used during the synthesis.

• 主な応用

  Dietary and medicinal applications
  Zinc acetate is used as a dietary supplement and in lozenges used to treat the common cold. Zinc acetate alone is thought to be a more effective treatment than zinc gluconate. Zinc acetate can also be used to treat zinc deficiencies. As an oral daily supplement it is used to inhibit the body's absorption of copper as part of the treatment for Wilson's disease. Zinc acetate is also sold as an astringent in the form of an ointment, a topical lotion; or combined with an antibiotic such as erythromycin for the topical treatment of acne. Furthermore Zinc acetate is commonly sold as a topical anti-itch ointment.
  Industrial applications
  Industrial applications include wood preserving, manufacturing other zinc salts, polymers, manufacture of ethylene acetate, as a dye mordant, and analytical reagent. Zinc acetate is a precursor via a sol-gel route to the transparent semi conductor zinc oxide. Zinc acetate is also used for manufacturing glazers for painting on porcelain; as a reagent in testing for albumin, tannin, phosphate; as cross-linking agents for polymers; in tobacco smoke filters; and as a topical fungicide.

• 安全性

  亜鉛酢酸塩は一般に人体に対して低毒性であるとされていますが大量に摂取すると健康に害を及ぼす可能性がありますまた環境への放出を避けるため使用後の処理には注意が必要です特に水系環境への放出は避けるべきです亜鉛酢酸塩が水生生物に与える影響はその濃度に依存しますが高濃度での曝露は有害な影響を及ぼす可能性が高いです

• 応用例（製薬）

  Zinc acetate has been used as an excipient in a variety of pharmaceutical formulations including topical gels, lotions, and solutions, and subcutaneous injections. It has also been investigated for use in an oral controlled-release formulation for water-soluble drugs in combination with sodium alginate and xanthan gum.
  Therapeutically, zinc acetate has been used in oral capsules for the treatment of Wilson’s disease. Zinc acetate has also been demonstrated to be effective as a spermicide in vaginal contraceptives.

• 材料の用途

  A novel formulation film based on zinc acetate and cellulose has been prepared. Hydroxyl ethyl cellulose (HEC) and Polyvinyl alcohol have mixed to form homogenous solution then zinc acetate with different ratios has been added. Research showed that Zinc/cellulose 1.5 films was superior in promoting burn wound healing via mechanisms possibly associated with its anti-inflammatory, anti-apoptotic, angiogenesis, and remodeling abilities^[1].

• 安全性

  Zinc acetate is used in topical pharmaceutical formulations and subcutaneous injections, where it is generally regarded as relatively nontoxic and nonirritant when used as an excipient. However, zinc acetate is poisonous by intravenous and intraperitoneal routes; it is also moderately toxic following oral consumption.
  Zinc acetate:
  LD50 (rat, oral): 2.510 g/kg
  LD50 (mouse, IP): 0.057 g/kg

• 貯蔵

  Zinc acetate loses water of hydration above 101℃. Zinc acetate should be stored in an airtight container in a cool, dry, place.

• 不和合性

  Zinc acetate is incompatible with oxidizing agents, zinc salts, alkalis and their carbonates, oxalates, phosphates, and sulfides.

• 規制状況(Regulatory Status)

  Included in the FDA Inactive Ingredients Database (SC injections; topical lotions and solutions). Included in medicines licensed in the UK.

• 参考文献

  https://en.wikipedia.org/wiki/Zinc_acetate
  https://pubchem.ncbi.nlm.nih.gov/compound/Zinc_acetate_dihydrate#section=GHS-Classification

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二酢酸亜鉛 スペクトルデータ(¹HNMR、IR1、IR2、Raman)

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