酒石酸-1-カリウム

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H315：皮膚刺激

  H319：強い眼刺激

• 注意書き

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P302+P352：皮膚に付着した場合：多量の水と石鹸で洗うこと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P332+P313：皮膚刺激が生じた場合：医師の診断/手当てを受けるこ と。

  P337+P313：眼の刺激が続く場合：医師の診断/手当てを受けること。

酒石酸-1-カリウム 価格

MSDS Information

• L(+)-Potassium hydrogen tartrate

酒石酸-1-カリウム 化学特性,用途語,生産方法

• 外観

  無色の結晶又は白色の結晶性の粉末

• 溶解性

  水、エタノール及びジエチルエーテルにほとんど溶けず、熱水にやや溶けにくく、無機酸、アンモニア水及び水酸化アルカリ溶液に溶ける。

• 解説

  ブドウ酒の製造中に発酵が進んで，エタノール濃度が高くなったときに析出する結晶．主成分は酒石酸水素カリウム(通常80 ％以上)で，再結晶して比較的純粋にしたものを酒石英という．

• 用途

  膨張剤(製菓、製パン、そう采など)(炭酸ナトリウムと配合)。

• 効能

  下剤

• 説明

  L (+)-Potassium hydrogen tartrate (also known as potassium bitartrate) is the potassiumacid salt of tartaric acid (a carboxylic acid). It is the byproduct during the winemaking process. It can be used in baking or as a cleaning solution. When mixed with an acidic liquid such as lemon juice or white vinegar, it can be made of a paste-like cleaning agent for metals or some other cleaning applications. It can also be used as a pH buffer component in chemistry. It has been recently shown that it is capable of treating breast cancer.
  
  Approved by the FDA as a direct food substance, potassium bitartrate is used as an additive, stabilizer, pH control agent, antimicrobial agent, processing aid, or thickener in various food products. Potassium bitartrate has a long history of medical use as a laxative administered as a rectal suppository and is an approved third-class OTC drug in Japan. Potassium bitartrate was one of active ingredients in Phexxi, a non-hormonal contraceptive agent that was approved by the FDA on May 2020.

• 化学的特性

  Potassium Bitartrate, or tartar, is a salt produced from the crystalsfound on the sides of wine casks. When purified it is known as cream oftartar. It is acid, and is slightly soluble in water.It is used in baking powder, for medicine, and as an acid and buffer in foods.

• 天然物の起源

  Potassium bitartrate crystallizes in wine casks during the fermentation of grape juice, and can precipitate out of wine in bottles.The crystals (wine diamonds) will often form on the underside of a cork in wine-filled bottles that have been stored at temperatures below 10°C , and will seldom, if ever, dissolve naturally into the wine.
  These crystals also precipitate out of fresh grape juice that has been chilled or allowed to stand for some time. To prevent crystals forming in homemade grape jam or jelly, fresh grape juice should be chilled overnight to promote crystallisation. The potassium bitartrate crystals are removed by filtering through two layers of cheesecloth. The filtered juice may then be made into jam or jelly. In some cases they adhere to the side of the chilled container, making filtering unnecessary.
  The crude form (known as beeswing) is collected and purified to produce the white, odorless, acidic powder used for many culinary and other household purposes.

• 使用

  Largely in baking powders; coloring metals, galvanic tinning of metals; reducer of CrO3 in mordants for wool.

• 主な応用

  In food
  In food, potassium bitartrate is used for:
  Stabilizing egg whites, increasing their heat tolerance and volume
  Stabilizing whipped cream, maintaining its texture and volume
  Preventing sugar syrups from crystallising
  Reducing discolouration of boiled vegetables
  Thickening Tartar sauce
  Additionally it is used as a component of: Baking powder, as an acid ingredient to activate baking soda Sodium-free salt substitutes, in combination with potassium chloride
  A similar acid salt, sodium acid pyrophosphate, can be confused with cream of tartar because of their common function as a component of baking powder.
  House hold use
  Potassium bitartrate can be mixed with an acidic liquid such as lemon juice or white vinegar to make a paste - like cleaning agent for metals such as brass, aluminum or copper, or with water for other cleaning applications such as removing light stains from porcelain.
  This mixture is sometimes mistakenly made with vinegar and sodium bicarbonate (baking soda), which actually react to neutralise each other, creating carbon dioxide and a sodium acetate solution. Cream of tartar was often used in traditional dyeing where the complexing action of the tartrate ions were used to adjust the solubility and hydrolysis of mordant salts such as tin chloride and alum.
  Cream of tartar, when mixed into a paste with hydrogen peroxide, can be used to clean rust from some hand tools, notably hand files. The paste is applied and allowed to set for a few hours and then washed off with a baking soda/water solution.
  Chemistry
  Potassium acid tartrate, also known as potassium hydrogen tartrate, is, according to NIST, used as a primary reference standard for a pH buffer. .

• 製造方法

  potassium bitartrate is mainly produced from the mother liquor of Seignette's salt. These decolorized, purified, and filtered solutions are acidified to pH 3.5 with hydrochloric or sulfuric acid. Since cream of tartar is sparingly soluble, it precipitates and is recovered by centrifugation, dried, and ground before being packaged as fine powder.

• 一般的な説明

  Potassium L-tartrate is found naturally in grapes. Its removal is necessary during wine making as it can precipitate, which is undesirable.

• 純化方法

  It crystallises from water (17mL/g) between 100o and 0o. Dry it at 110o. [Beilstein 3 IV 1222.]

• 参考文献

  Coulter, A. D, et al. "Potassium bitartrate crystallisation in wine and its inhibition." Australian Journal of Grape & Wine Research 21.S1(2016):627-641.
  Berg, H. W, and M. Akiyoshi. "Utility of potassium bitartrate concentration-product values in wine processing." Amer J Enol Vitic (1971).
  Cremer, G. A., and R. Boulton. "The hydrolysis of gelatin by an immobilized acid protease. I. Immobilization and hydrolysis kinetics. " American Journal of Enology & Viticulture 1(1981):14-17.
  Dr, María J. Vicent, et al. "The Therapeutic Action of Potassium Bitartrate." Angewandte Chemie 44.26(2005):4061-6.

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