4-ニトロビフェニル

化学名:4-ニトロビフェニル

CAS番号.92-93-3

英語名:4-Nitrobiphenyl

CBNumberCB7482649

MFC12H9NO2

MW199.21

MOL File92-93-3.mol

别名

4-フェニル-1-ニトロベンゼン

p-ニトロジフェニル

1-ニトロ-4-フェニルベンゼン

4-ニトロビフェニル物理性質

融点	114 °C
沸点	340 °C
比重(密度)	1.1919 (rough estimate)
屈折率	1.5880 (estimate)
闪点	43 °C
溶解性	酢酸、ベンゼン、クロロホルム、エーテルに可溶 (Weast, 1986)
外見	個体
色	白い
水溶解度	不溶性
安定性：	安定。強力な酸化剤とは相容れない。
InChI	InChI=1S/C12H9NO2/c14-13(15)12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H
InChIKey	BAJQRLZAPXASRD-UHFFFAOYSA-N
SMILES	C1(C2=CC=CC=C2)=CC=C([N+]([O-])=O)C=C1
CAS データベース	92-93-3(CAS DataBase Reference)
IARC	3 (Vol. 4, Sup 7) 1987
NISTの化学物質情報	1,1'-Biphenyl, 4-nitro-(92-93-3)
EPAの化学物質情報	4-Nitrobiphenyl (92-93-3)

安全性情報

主な危険性	T,N
Rフレーズ	45-51/53
Sフレーズ	53-45-61
RIDADR	2811
RTECS 番号	DV5600000
国連危険物分類	6.1(b)
容器等級	III
HSコード	29042090
有毒物質データの	92-93-3(Hazardous Substances Data)
毒性	Acute oral LD₅₀ for rats 2,230 mg/kg, rabbits 1,970 mg/kg (quoted, RTECS, 1985).

危険有害性情報のコード(GHS)

MSDS Information

4-ニトロビフェニル化学特性,用途語,生産方法

用途
合成中間体
化学的特性
4-Nitrobiphenyl exists as yellow plates or needles..
使用
4-Nitrobiphenyl has some uses as a plasticizer, fungicide, and wood preservative.
一般的な説明
White to yellow needle-like crystalline solid with a sweetish odor.
空気と水の反応
Insoluble in water.
反応プロフィール
4-Nitrobiphenyl is incompatible with the following: Strong reducers .
危険性
Toxic by ingestion and skin contact. Confirmed carcinogen.
健康ハザード
p-Nitrobiphenyl (PNB) is a urinary bladder carcinogen in dogs.
安全性プロファイル
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS OF AROMATIC HYDROCARBONS.
毒性学
4-Nitrobiphenyl is no longer manufactured or used in the United States. Limited information is available on the health effects of 4-nitrobiphenyl. Acute (short-term) exposure to 4-nitrobiphenyl in humans results in irritation of the eyes, mucous membranes, and respiratory tract, such as headache, nausea, vomiting, and fatigue. Chronic (long-term) exposure to high concentrations of 4-nitrobiphenyl in workers has resulted in effects on the peripheral and central nervous systems as well as the liver and kidney. No information on the reproductive, developmental, or carcinogenic effects of 4-nitrobiphenyl in humans is available. EPA has not classified 4-nitrobiphenyl for carcinogenicity. 4-Nitrobiphenyl is no longer manufactured, imported, used, or sold in the United States.
職業ばく露
4-Nitrobiphenyl was formerly used in the synthesis of 4-aminodiphenyl. It is presently used only for research purposes; there are no commercial uses.
発がん性
The case for the carcinogenicity of PNB is supported by (1) the induction of urinary bladder cancer in dogs after administration of PNB; (2) the evidence that PNB is metabolized in vivo to 4-aminobiphenyl (a potent carcinogen); and (3) the possibility that the cases of human urinary bladder cancer attributed to 4- aminobiphenyl may also have been induced by exposure to PNB.1
輸送方法
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
不和合性
Incompatible with strong reducing agents such as hydrides, oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
廃棄物の処理
Incineration @ 982℃/2.0 seconds (minimum) with scrubbing for nitrogen oxides abatement.

4-ニトロビフェニル上流と下流の製品情報

4-ニトロビフェニル生産企業

4-ニトロビフェニルスペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、IR3、MS、Raman)

92-93-3, 4-ニトロビフェニルキーワード

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4-ニトロビフェニル

危険有害性情報のコード(GHS)

MSDS Information

4-ニトロビフェニル 化学特性,用途語,生産方法

4-ニトロビフェニル 上流と下流の製品情報

4-ニトロビフェニル 生産企業

4-ニトロビフェニル スペクトルデータ(1HNMR、13CNMR、IR1、IR2、IR3、MS、Raman)

92-93-3, 4-ニトロビフェニル キーワード

4-ニトロビフェニル化学特性,用途語,生産方法

4-ニトロビフェニル上流と下流の製品情報

4-ニトロビフェニル生産企業

4-ニトロビフェニルスペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、IR3、MS、Raman)

92-93-3, 4-ニトロビフェニルキーワード