CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE

CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE 化学特性,用途語,生産方法

• 純化方法

  Recrystallise it from hot dilute HCl, and on cooling it gives the red dihydrate. The trihydrate crystallises slowly from a cold aqueous solution and is dried in air. The red dihydrate can be obtained from the trihydrate by desiccation over conc H2SO4, by washing with EtOH or by precipitating from a warm aqueous solution with HCl. The dihydrate is also formed by decomposing the black trihydrate form by heating in water (slowly), or more rapidly with hot 2N HCl. [Morgan & Burstall J Chem Soc 1498 1934, Lippard Acc Chem Res 11 211 1987.]

CHLORO(2,2':6',2''-TERPYRIDINE)PLATINUM(II) CHLORIDE DIHYDRATE 生産企業

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