金(III)トリブロミド

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H314：重篤な皮膚の薬傷?眼の損傷

• 注意書き

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P310：ただちに医師に連絡すること。

金(III)トリブロミド 価格

金(III)トリブロミド 化学特性,用途語,生産方法

• 外観

  暗褐色～黒色、結晶～結晶性粉末

• 使用上の注意

  アルゴン封入。

• 化学的特性

  Yellowish-gray mass. Decomposes at approximately 165C. Insoluble in water.

• 使用

  Gold(III) bromide is used as a catalyst in a variety of reactions. It catalyzes the reaction between an enynal unit and carbonyl compounds to form a six-membered cyclic compound. Another catalytic use of gold tribromide is in the nucleophilic substitution reaction of propargylic alcohols, with the gold complex acting as an alcohol-activating agent to facilitate the substitution. It can be used as a testing reagent for the presence of ketamine.

• 定義

  Brownish-black powder. Mp 160C with decomposition. Soluble in water and alcohol.

• 純化方法

  Purify it by adding pure Br2 to the dark powder, securely stopper the container, warm a little and shake while keeping away from light for ca 48hours. Remove the stopper and place it over NaOH until free Br2 is no longer in the apparatus (48-60hours). The bright yellow needles of the tribromide are stable over NaOH in the dark. It is soluble in H2O and in EtOH where it is slowly reduced. Keep it in a cooled, closed container and protect it from light as decomposition causes free gold to be formed. Aurobromic acid can be obtained by adding the calculated amount of conc HBr to AuBr3 (actually Au2Br6) until all dissolves, whereby the acid crystallises out as HAuBr4.5H2O; a deliquescent solid soluble in EtOH with m ca 27o, and store it as above. [Gibson & Colles J Chem Soc 2411 1931, Burawoy & Gibson J Chem Soc 217 1935, Burawoy & Gibson J Chem Soc 219 1935.]

金(III)トリブロミド 生産企業

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