(1'α)-6',7-エポキシ-6,12'-ジメトキシ-2'-メチルオキシアカンタン

(1'α)-6',7-エポキシ-6,12'-ジメトキシ-2'-メチルオキシアカンタン 化学特性,用途語,生産方法

• 説明

  A bisbenzylisoquinoline alkaloid, this base has been isolated from Cocculus sarmentosus Diels and C. trilobus DC. It crystallizes as colourless prisms and is dextrorotatory with [α]²⁹_D + 296.3° (CHCI3). Both the hydrochloride and hydro_x0002_bromide are crystalline and sparingly soluble in H20 and the dimethiodide has m.p. 273°C (dec.). Two methoxyl groups and two methylimino groups are present. With dimethyl sulphate in NaOH, the base yields trilobinemethylmethine as long, colourless prisms, m.p. 106° C which is optically inactive and on ozonization furnishes 2-methoxy-5:4'-dialdehydodiphenyl ether, m.p. 72-5°C and a complex dialdehyde, m.p. 124°C.

• 参考文献

  Kondo, Tomita., J. Pharm. Soc., Japan, 47, 39 (1927)
  Kondo, Tomita., ibid, 48, 83 (1928)
  Kondo, Tomita., ibid, SO, 91 (1930)
  Faltis., Annalen, 497,69 (1932)
  Kondo, Tomita., Arch. Pharm., 274, 65 (1936)
  Faltis et al., Ber., 74,79 (1941)

(1'α)-6',7-エポキシ-6,12'-ジメトキシ-2'-メチルオキシアカンタン 上流と下流の製品情報

(1'α)-6',7-エポキシ-6,12'-ジメトキシ-2'-メチルオキシアカンタン 生産企業

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