シクロヘキサンメタノール

化学名:シクロヘキサンメタノール

CAS番号.100-49-2

英語名:Cyclohexanemethanol

CBNumberCB6193973

MFC7H14O

MW114.19

别名

シクロヘキサンメタノール

シクロヘキシルカルビノール

ヒドロキシメチルシクロヘキサン

シクロヘキサンメタノール物理性質

融点	-43°C
沸点	181 °C (lit.)
比重(密度)	0.928 g/mL at 25 °C (lit.)
屈折率	n20/D 1.465(lit.)
闪点	160 °F
貯蔵温度	Store below +30°C.
溶解性	エーテル、アルコールに可溶。
酸解離定数(Pka)	15.17±0.10(Predicted)
外見	油
色	無色
Merck	14,2731
BRN	773712
Dielectric constant	9.7（60℃）
InChI	1S/C7H14O/c8-6-7-4-2-1-3-5-7/h7-8H,1-6H2
InChIKey	VSSAZBXXNIABDN-UHFFFAOYSA-N
SMILES	OCC1CCCCC1
CAS データベース	100-49-2(CAS DataBase Reference)
NISTの化学物質情報	Cyclohexanemethanol(100-49-2)
EPAの化学物質情報	Cyclohexanemethanol (100-49-2)

安全性情報

危険有害性情報のコード(GHS)

外観
無色～うすい黄色, 澄明の液体
溶解性
アセトンに極めて溶けやすく、水にほとんど溶けない。
用途
有機合成用原料。
説明
Cyclohexanemethanol is a cycloalkanol compound primarily used in organic synthesis for the preparation of other heterocyclic compounds. Under the action of a CaO catalyst (pre-calcined at 300°C), cyclohexanemethanol can be employed in ester exchange reactions to produce various fine chemicals, and is also utilised in the synthesis of polyester compounds.
化学的特性
Colorless liquid
使用
Cyclohexanemethanol used as solvents, fuels . It is also used in pharmaceuticals, plasticizers, surfactants, lubricants, ore floatation agents, hydraulic fluids, and detergents.
Synthesis Reference(s)
Tetrahedron Letters, 36, p. 1059, 1995 DOI: 10.1016/0040-4039(94)02453-I
合成
To 1 g benzyl alcohol in 40 ml of H20, HRO/Na- β catalyst (50 mg) was added in a reactor vessel. The reactor vessel was then heated at 100 °C for 1 h under H2 pressure (20 bar). After completion of the reaction, the catalyst was separated by using centrifuge and the obtained clear product mixture was analyzed by GC-MS. The reaction gave 100% conversion of benzyl alcohol with 100% yield of Cyclohexanemethanol.

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