トリクロロチタン(III)

化学名:トリクロロチタン(III)

CAS番号.7705-07-9

英語名:Titanous chloride

CBNumberCB5375851

MFCl2Ti

MW118.77

MOL File7705-07-9.mol

别名

三塩化チタン

チタン(III)トリクロリド

トリクロロチタン(III)

トリクロロチタン(III)物理性質

融点	440 °C (dec.)(lit.)
沸点	100 °C
比重(密度)	1.192 g/mL at 25 °C
溶解性	reacts with H2O
外見	粉
色	紫の
水溶解度	溶ける
Sensitive	Air Sensitive
Merck	14,9481
安定性：	安定していますが、水と激しく反応し、空気中で自然発火します。
InChIKey	ZWYDDDAMNQQZHD-UHFFFAOYSA-L
CAS データベース	7705-07-9(CAS DataBase Reference)
NISTの化学物質情報	Titanium(iii) chloride(7705-07-9)
EPAの化学物質情報	Titanium chloride (TiCl3) (7705-07-9)

安全性情報

主な危険性	C,F
Rフレーズ	34-37-35-17-14
Sフレーズ	6-26-30-36/37/39-43-45
RIDADR	UN 3264 8/PG 2
WGK Germany	3
RTECS 番号	XR1924000
F	10-23
TSCA	Yes
国連危険物分類	8
容器等級	II
HSコード	28273990
化審法	1-905
安衛法	特定化学物質障害予防規則:第3類物質,57,57-2
毒劇物取締法	III

危険有害性情報のコード(GHS)

トリクロロチタン(III) 価格

製品番号	包装	価格	製品説明	購入
富士フイルム和光純薬株式会社(wako) W01W0120-1280	500g	￥5400	塩化チタン(III)溶液	購入
関東化学株式会社(KANTO) 40172-96	7.5mL×5	￥9000	塩化チタン（ＩＩＩ）溶液 >20.0%(T)	購入
関東化学株式会社(KANTO) 40172-01	500mL	￥4700	塩化チタン（ＩＩＩ）溶液 >20.0%(T)	購入
Sigma-Aldrich Japan 14010	250ML	￥4640	塩化チタン(III) 溶液 ≥12% TiCl3 basis	購入
Sigma-Aldrich Japan 14010	1L	￥15800	塩化チタン(III) 溶液 ≥12% TiCl3 basis	購入

MSDS Information

トリクロロチタン(III) 化学特性,用途語,生産方法

外観
暗紫色の液体
溶解性
水及び塩酸に易溶。エタノールに可溶, エーテルに不溶。
用途
還元剤、規定液として色素の定量(容量分析)。酸化チタン膜の合成研究，釉薬研究等。
用途
オレフィン類の重合触媒原料
化学的特性
purple crystalline solid
物理的性質
Red-violet hexagonal crystals; hygroscopic; density 2.64 g/cm³; decomposes on heating above 425°C; also decomposes in water, evolving heat; soluble in alcohol, acetonitrile and certain amines; insoluble in hydrocarbons and ether.
使用
As powerful reducing agent, Titanous chlorideb can reduces nitrate to ammonia; when boiled with aqueous SO2, sulfur is separated; hence is used as an aqueous solution for estimation of nitro groups, ferric ions, per-salts, etc. Removes stains, etc. (stripper) in laundering.
製造方法
Titanium trichloride may be prepared by reducing titanium tetrachloride with hydrogen at 600°C. The tetrachloride may alternatively be reduced with aluminum, zinc, magnesium, tin, or by electrolysis.
一般的な説明
A dark violet crystalline solid. Denser than water. Contact may burn skin, eyes, and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.
空気と水の反応
Pyrophoric, very reactive with water and moisture in air produces hydrochloric acid, [Merck 11th ed. 1989]. Ignites spontaneously on contact with air; decomposed by water and water vapor forming HCl. [Handling Chemcials Safely 1980. p. 905].
反応プロフィール
Acidic salts, such as TITANIUM TRICHLORIDE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. Ethylene can polymerize at low pressure if catalyzed by titanium halides. (Sundaram, K. M, M. M. Shreehan, E. F. Olszewski. thylene. Kirk-Othmer Encyclopedia of Chemical Technology. John Wiley & Sons, Inc. 2001.)
危険性
Fire risk in the presence of oxidizing materials. Irritant to skin and tissue; open container only in oxygen-free or inert atmosphere.
健康ハザード
Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
火災危険
Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.
安全性プロファイル
A corrosive irritant to skin, eyes, and mucous membranes. A severe corrosive because it liberates heat and hydrochloric acid upon contact with moisture. If spilled on slun, wipe off with dry cloth before applying water. May ignite spontaneously in air. Flammable when exposed to heat or flame. Reacts violently with K, HF. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of Cl-. See also TITANIUM COMPOUNDS.
純化方法
It is a brown purple powder that is very reactive to H2O and pyrophoric when dry. It should be manipulated in a dry box. It is soluble in CH2Cl2 and tetrahydrofuran, and is used as a M solution in these solvents in the ratio of 2:1, and stored under N2. It is a powerful reducing agent. [Ingraham et al. Inorg Synth VI 52 1960.]

トリクロロチタン(III) 上流と下流の製品情報

トリクロロチタン(III) 生産企業

トリクロロチタン(III) スペクトルデータ(ESR)

7705-07-9, トリクロロチタン(III) キーワード

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