9-アントラセンボロン酸

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H301：飲み込むと有毒

• 注意書き

  P301+P310：飲み込んだ場合：直ちに医師に連絡すること。

9-アントラセンボロン酸 価格

9-アントラセンボロン酸 化学特性,用途語,生産方法

• 外観

  わずかにうすい黄色～うすい褐色、結晶性粉末～粉末

• 使用上の注意

  窒素封入

• 説明

  9-Anthraceneboronic acid is a boronic acid compound mainly used as an organic synthesis and reaction reagent. The addition of 9-Anthraceneboronic acid introduces a borate ester bond and an anthracene functional group into ordinary polyvinyl alcohol, which can be used to prepare the composite material poly(vinyl alcohol) anthraceneboronic acid (PVA-ABA), which is suitable for sustainable engineering applications due to its high mechanical strength and toughness, good water resistance, chemical durability, and ease of recycling. It can also be used to prepare stimuli-responsive polymeric materials and highly efficient luminescent materials.

• 化学的特性

  Tan solid

• 使用

  suzuki reaction

• 合成

  9-bromoanthracence (10.0 g, 38.9 mmol) was dissolved in an anhydrous THF solution (500 mL) and stirred at ?78C. Then, 1.6 M n-BuLi (29.3 mL,46.7 mmol) was added. Triethyl borate (9.3 mL, 54.5 mmol) was added to the reaction after 30 min. After the reaction, the solution was acidified with 2 N HCl solution at room temperature and extracted with ethyl acetate and water. The organic layer was dried with anhydrous MgSO4 and filtered. The solution was evaporated. The residue was dissolved in hexane and added to ethyl acetate. The precipitate was filtered and washed with hexane to obtain a beige compound 9-Anthraceneboronic acid (7.70 g, 89 percent).

• 純化方法

  Crystallise the boronic acid from dilute HCl (m 180-184o). The disodium salt has m 209-213o. [Beilstein 16 IV 1679.]

• 参考文献

  [1] Qizhou Sang and Zixing Shi*. “Waterproof, Chemically Durable, and Closed-Loop Recyclable Poly(vinyl alcohol) Plastic Enabled by Dynamic Covalent Modification.” ACS Applied Polymer Materials 5 11 (2023): 9403–9412.
  [2] Zhiyong Liu. “Integrating Boronic Esters and Anthracene into Covalent Adaptable Networks toward Stimuli-Responsive Elastomers.” Polymers (2022).

9-アントラセンボロン酸 上流と下流の製品情報

9-アントラセンボロン酸 生産企業

Global(385)Suppliers

100622-34-2, 9-アントラセンボロン酸 キーワード