ヒドラジン一水和物

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H226：引火性の液体および蒸気

  H314：重篤な皮膚の薬傷?眼の損傷

  H317：アレルギー性皮膚反応を起こすおそれ

  H330：吸入すると生命に危険

  H350：発がんのおそれ

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

ヒドラジン一水和物 価格

MSDS Information

• Hydrazine hydrate

ヒドラジン一水和物 化学特性,用途語,生産方法

• 外観

  無色澄明の液体

• 溶解性

  水、エタノール及びアセトンに極めて溶けやすい。

• 用途

  プラスチック発泡剤、洗浄剤、重合触媒

• 用途

  清缶剤、ゴム薬品

• 用途

  ロケット燃料(無水ヒドラジン),以下は水和物の用途:ヒドラジン化合物原料,分析用試薬,還元剤,溶剤,医薬?農薬原料,清缶剤

• 化学的特性

  colourless fuming liquid

• 物理的性質

  Colorless fuming liquid; faint odor; refractive index 1.4284; density 1.032g/mL; boils at 119°C; solidifies at -51.7°C; miscible with water and alcohol;insoluble in chloroform, methylene chloride, and ether.

• 使用

  Hydrazine hydrate is used as a reducing agent in synthetic and analytical reactions and as a solvent for many inorganic compounds. It also is used with methanol as a propellant for rocket engines. Another application is catalytic decomposition of hydrogen peroxide.

• 製造方法

  Hydrazine hydrate is prepared by treating hydrazine sulfate, N2H4•H2SO4 with sodium hydroxide. The product is collected by distillation under nitrogen. It also is obtained as a by-product in the Bayer Ketazine process for producing hydrazine in which hydrazine solution is hydrolysed under pressure in a ketazine column.

• 一般的な説明

  A colorless fuming liquid with a faint ammonia-like odor. Corresponds to a 64% aqueous solution of hydrazine in water. Combustible but may require some effort to ignite. Contact with oxidizing materials may cause spontaneous ignition. Toxic by inhalation and by skin absorption. Corrosive to tissue. Produces toxics oxides of nitrogen during combustion.

• 空気と水の反応

  Fumes in air. Water soluble.

• 反応プロフィール

  Hydrazine hydrate is a base and a very powerful reducing agent. Very corrosive. Violent reaction on contact with alkali metals (sodium, potassium), 2,4-dinitrochlorobenzene, tin dichloride, mercury oxide. Vigorous neutralization reaction with acids. Emits toxic fumes of nitrogen oxides when heated to decomposition [Lewis, 3rd ed., 1993, p. 680]. Reacts with tin(II) chloride to give tin(II) dihydrazine chloride, which decomposes explosively when heated [Mellor 7:430(1946-1947)]. Reacts exothermically and violently with 2,4-dinitrochlorobenzene [Wischmeyer (1967)].

• 危険性

  See hydrazine.

• 健康ハザード

  TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

• 火災危険

  Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

• 合成方法

  アンモニアを次亜塩素酸ナトリウムで酸化して水和ヒドラジンを得る．水ヒドラジンは，水加ヒドラジンにキシレンを加えて蒸留するか，強アルカリと接触させて脱水して得る

• 純化方法

  It is best obtained by heating hydrazine sulphate (200g), NaOH (160g) and H2O (75mL, exothermic) in a copper flask under reflux for 1.5hours then distilled off (using a flame to remove all the hydrazine). The distillate (175mL) is a clear liquid which contains ~40-45% of N2H4. Note that hydrazine attacks glass, rubber and cork, and stainless steel equipment should be used. The percentage of hydrazine is determined by titration with standard acid (methyl orange indicator) or against standard iodine (starch indicator). Hydrazine monohydrate should contain 64% of N2H4. The ~40-45% solution may be concentrated by mixing it (144mL) with xylene (230mL) and distilling it through an efficient fractionating column (e.g. Hempel column, p 10). All the xylene passes over with about 85mL of H2O. On distilling the residue, hydrated hydrazine (50mL) is obtained containing 80-85% of N2H4. This can be diluted with conductivity H2O to 64% N2H4 to give the monohydrate. Hydrazine and its hydrates have VERY IRRITATING and TOXIC vapours and should be used in an efficient fume cupboard. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I pp 469-472 1963.]

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