1,3-ジクロロプロペン (cis-, trans-混合物)

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H226：引火性の液体および蒸気

  H304：飲み込んで気道に侵入すると生命に危険のおそ れ

  H315：皮膚刺激

  H317：アレルギー性皮膚反応を起こすおそれ

  H319：強い眼刺激

  H332：吸入すると有害

  H335：呼吸器への刺激のおそれ

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P310：飲み込んだ場合：直ちに医師に連絡すること。

  P303+P361+P353：皮膚（または髪）に付着した場合：直ちに汚染された衣 類をすべて脱ぐこと/取り除くこと。皮膚を流水/シャワー で洗うこと。

  P331：無理に吐かせないこと。

1,3-ジクロロプロペン (cis-, trans-混合物) 価格

MSDS Information

• 1,3-Dichloropropene

1,3-ジクロロプロペン (cis-, trans-混合物) 化学特性,用途語,生産方法

• 外観

  無色～黄色, 澄明の液体

• 溶解性

  水に不溶, アルコール, アセトンに易溶。エタノール及びアセトンに極めて溶けやすく、水にほとんど溶けない。

• 用途

  有機合成原料(農薬)、薫蒸剤。

• 説明

  This nematocide is used as a sol fumigant prior to crop cultivation. Mainly farmers and process operators employed at pesticide plants are exposed.

• 化学的特性

  1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.

• 使用

  1,3-Dichloropropene (a technical-grade mixture of the cis-and transisomers) is used as a preplanting fumigant, mainly for the control of nematodes affecting the roots of plants, selected plant diseases, garden centipedes, wireworms, and weeds; as a solvent; and as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides. It is registered for use on all vegetable, fruit, and nut crops, all forage crops, tobacco, all fiber crops, and all nursery crops (EPA 1998). In Hawaii, 1,3-dichloropropene is used to control nematodes on pineapples at planting (Albrecht 1987). In 2009, three products containing 1,3-dichloropropene as an active ingredient were registered for restricted, non-residential use in the United States (EPA 2009). No products containing 1,3-dichloropropene are registered for use by homeowners (EPA 1998).

• 調製方法

  1,3-DCP is produced either by high-temperature chlorination of propylene or from 1,3-dichloro-2-propanol by dehydration with phosphoryl chloride or phosphorus pentoxide in benzene. All commercial preparations of 1,3-DCP are mixtures of the cis- and trans-isomers.
  According to SRI Consulting, Dow AgroSciences LLC (Freeport, Texas) is the only current manufacturer of 1,3- DCP. Active registrants of 1,3-DCP pesticide formulations include Dow AgroSciences LLC (Indianapolis, Indiana),Soil Chemicals Corporation (Hollister, California), and Trical (Hollister, California).

• 一般的な説明

  A clear colorless liquid. Flash point 95°F. Denser (at 10.2 lb / gal) than water and insoluble in water. Vapors are heavier than air. Used to make other chemicals and as soil fumigant.

• 空気と水の反応

  Highly flammable. Insoluble in water.

• 反応プロフィール

  1,3-Dichloropropene reacts vigorously with oxidizing materials. Reacts with aluminum, active metals, and halogenated compounds. Also reacts with acids and thiocyanates. Corrosive to magnesium, magnesium alloys and aluminum alloys. Incompatible with some metal salts .

• 健康ハザード

  VAPOR: Irritating to eyes, nose and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed.

• 火災危険

  FLAMMABLE. POISONOUS GASES ARE PRODUCED IN FIRE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Toxic and irritating gases may be generated.

• 作用机制

  線虫などにとって必須の酵素に含まれるチオール基やヒドロキシ基などの求核中心と反応することによりその酵素を阻害し，活性を発揮する。

• 农业用途

  Soil fumigant, Nematicide: This chemical is also used in combinations with dichloropropanes as a soil fumigant to kill nematodes, insects and fungus on cotton, potatoes, tobacco, sugar beets, vegetables, grain, citrus planting sites, deciduous fruit and nut-tree planting sites, and ornamental trees and floral sites. Top four applications in California are on sweet potatoes, carrots, wine grapes and outdoor propagation nurseries. It is used on a wide variety of crops. Not approved for use in EU countries. Actively registered in the U.S.

• 製品名

  DURHAM NEMATOCIDE®[C]; FUMAZONE®[C]; NEMAGON®[C]; NEMEX®; PROKILL NEMATOCIDE®[C]; TELONE®; TELONE II®; TELONE II-B®; TELONE® EC DRIP; VIDDEN D®; VORLEX®

• 接触アレルゲン

  This nematocide is used as a soil fumigant prior to crop cultivation. Farmers and process operators employed at pesticide plants are mainly exposed

• 安全性プロファイル

  Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. Mildly toxic by inhalation. A strong irritant. Mutation data reported. A pesticide. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidzers. Reacts vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and CHLORIDES.

• 職業ばく露

  Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.

• 発がん性

  Technical-grade 1,3-dichloropropene (co ntaining 1.0% epichlorohydrin as a stabilizer) is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. The technical-grade 1,3-dichloropropene used in the cancer studies in experimental animals was a mixture of cis- and trans-isomers and varied in purity and the stabilizer used (see Properties).

• 代謝経路

  Degradation of 14C-1,3-dichloropropene in aerobic soils in the dark at 25℃ at concentration of approximately 100 μg g^-1 results in the formation of 3-chloroallyl alchohol, 3-chloroacrylic acid, numerous minor carboxylic acid metabolites, and carbon dioxide. In addition, there is extensive incorporation of 14C labeled material into the soil organic matter in the soils. By a specific bacterium (Pseudomonas cichorii 170) which is isolated from soil, 1,3-dichloropropene is degraded in different pathways from those of soil degradation. The terminal degradate by this bacterium is acetoaldehye which undergoes mineralization.

• 輸送方法

  UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.

• 不和合性

  Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.

• 廃棄物の処理

  Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

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