1,6-ヘキサンジオール

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H315：皮膚刺激

  H319：強い眼刺激

  H335：呼吸器への刺激のおそれ

• 注意書き

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P302+P352：皮膚に付着した場合：多量の水と石鹸で洗うこと。

  P304+P340：吸入した場合：空気の新鮮な場所に移し、呼吸しやすい 姿勢で休息させること。

1,6-ヘキサンジオール 価格

MSDS Information

• Hexamethylene glycol

1,6-ヘキサンジオール 化学特性,用途語,生産方法

• 外観

  白色～ほとんど白色, フレーク

• 定義

  本品は、次の化学式で表される有機化合物である。

• 溶解性

  水, エタノール, アセトンに可溶。

• 用途

  ポリウレタン、ポリエステル原料、エポキシ樹脂希釈剤

• 化粧品の成分用途

  溶剤

• 主な用途／役割

  ポリウレタン樹脂系接着剤の原料として使用される。

• 使用上の注意

  夏季には室温で融解することがありますので、使用後は直ちに冷蔵保存して下さい。

• 化学的特性

  white waxy flakes

• 使用

  1,6-Hexanediol is used in polymer synthesis such as polyester, polyurethane and nylon. It is used as an intermediate to adhesives, acrylics and dyestuffs. Further, it is employed in gasoline refining and pharmaceutical production.

• 調製方法

  1,6-Hexanediol is produced industrially by the catalytic hydrogenation of adipic acid or of its esters. Mixtures of dicarboxylic acids and hydroxycarboxylic acids with C6 components formed in other processes (e.g., in cyclohexane oxidation) are also used. Esterifification of "distillation heavies" with lower alcohols is often carried out before hydrogenation. The acids are hydrogenated continuously at 170-240 ℃ and at 15.0-30.0 MPa on a suitable catalyst either in a trickle-flflow (downflflow) or a bubble-flflow (upflflow) fifixed-bed reactor. The reactor temperature is controlled by circulating part of the reactor discharge. The hydrogen required for the hydrogenation is fed together with the recycle gas through the recycle gas compressor to the reactor. Side products of the synthesis are alcohols, ethers, diols, and esters. Pure 1,6-hexanediol is obtained by fractional distillation of the crude reactor discharge. For the hydrogenation of dicarboxylic acids, catalysts containing cobalt, copper, or manganese are suitable. For the hydrogenation of esters, catalysts such as copper chromite or copper with added zinc and barium are used as "full catalysts" or on inert carriers. Ruthenium, platinum, or palladium on inert supports can also be used. Gas-phase hydrogenation of esters of adipic or 6-hydroxyhexanoic acid can be carried out at 1-7 MPa. Both acids and esters also may be hydrogenated using suspended catalysts. Oligomeric esters of the product diol and adipic acid can also be hydrogenated.

• 定義

  ChEBI: A diol that is hexane substituted by hydroxy groups at positions 1 and 6.

• 危険性

  Toxic by ingestion.

• 純化方法

  Fractionally crystallise it from its melt or from water. Distil it in vacuo. [Beilstein 1 IV 2556.]

• 参考文献

  [1] Yuji Itoh. “1,6-hexanediol rapidly immobilizes and condenses chromatin in living human cells.” ACS Applied Electronic Materials (2021).

1,6-ヘキサンジオール 上流と下流の製品情報

1,6-ヘキサンジオール 生産企業

Global(522)Suppliers

1,6-ヘキサンジオール スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS、Raman)

629-11-8, 1,6-ヘキサンジオール キーワード