アリルグリシジルエーテル

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H226：引火性の液体および蒸気

  H302：飲み込むと有害

  H315：皮膚刺激

  H317：アレルギー性皮膚反応を起こすおそれ

  H318：重篤な眼の損傷

  H331：吸入すると有毒

  H335：呼吸器への刺激のおそれ

  H341：遺伝性疾患のおそれの疑い

  H351：発がんのおそれの疑い

  H412：長期的影響により水生生物に有害

• 注意書き

  P210：熱/火花/裸火/高温のもののような着火源から遠ざ けること。－禁煙。

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P308+P313：暴露または暴露の懸念がある場合：医師の診断/手当てを 受けること。

アリルグリシジルエーテル 価格

MSDS Information

• Allyl 2,3-epoxypropyl ether

アリルグリシジルエーテル 化学特性,用途語,生産方法

• 外観

  無色～ほとんど無色, 澄明の液体

• 溶解性

  水に可溶 (14g/100ml水)。水、エタノール及びアセトンに溶けやすい。

• 用途

  シランカップリング剤の原料、アクリルゴムのコモノマー、アクリル繊維や羊毛の改質、接着材、塗料用樹脂、ポリウレタンゴゴムの耐寒、耐油化、ポリエーテルゴムのコモノマー等 。

• 主な用途／役割

  エポキシ樹脂接着剤の希釈剤として使用される。

• 化学的特性

  Allyl glycidyl ether is a stable, colorless, flammable liquid with a pleasant odor. It is incompatible with strong oxidizers agents, acids, and bases. It may form peroxides in storage if in contact with air.

• 物理的性質

  Clear, colorless, watery, combustible liquid with a strong, pleasant odor. An odor threshold value of 47 mg/m³ was reported (quoted, Verschueren, 1983).

• 使用

  Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered as the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyltrimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane.

• 調製方法

  AGE is manufactured through the condensation of allyl alcohol and epichlorohydrin with subsequent dehydrochlorination with caustic to form the epoxy ring.

• 一般的な説明

  A colorless liquid with a pleasant odor. Flash point 135°F. Slightly less dense than water and insoluble in water. Hence floats on water. Poisonous by ingestion and mildly toxic by inhalation and skin contact. Very irritating to skin and eyes. Used to make other chemicals.

• 空気と水の反応

  Flammable. Insoluble in water.

• 反応プロフィール

  Allyl glycidyl ether reacts violently with oxidizing agents. Can form peroxides. Polymerizes readily [Handling Chemicals Safely 1980. p.128].

• 危険性

  Skin, eye, and upper respiratory tract irri- tant, and dermatitis. Questionable carcinogen.

• 健康ハザード

  Occupational workers exposed to allyl glycidyl ether develop severe symptoms of poisoning that include, but are not limited to, irritation of the eyes, redness, pain, blurred vision, deep skin burns, respiratory system; causes damage of the mucous membranes, dermatitis, burning sensation, shortness of breath, headache, drowsiness, dullness, nausea, vomiting, pulmonary edema, narcosis, possible hematopoietic and reproductive effects. Acute exposure may cause CNS depression. The major target organs include the eyes, skin, respiratory system, blood, and the reproductive system.

• 火災危険

  HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

• 接触アレルゲン

  Allyl glycidyl ether is a monoglycidyl derivative, used as a reactive epoxy diluent for epoxy resins. As an impurity, it was considered to be the sensitizing agent in a plastic industry worker allergic to 3-glycidyloxypropyl trimethoxysilane, an epoxy silane compound used as a fixing additive in silicone and polyurethane

• 安全性プロファイル

  Confirmed animal carcinogen. Poison by ingestion. Moderately toxic by inhalation and skin contact. Mutation data reported. A severe skin and eye irritant. Can cause central nervous system depression and pulmonary edema. A flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical.When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS
   Allyl glycidyl ether has an LD50 of 390 mg/kg (mouse, oral) and an LD50 of 1600 mg/kg (rat, oral). In rabbits, the dermal LD50 is 2550 mg/kg. Inhalational toxicity has been estimated: LC50 = 270 ppm (mice, 4 h) and 670 ppm (rats, 8 h)

• 職業ばく露

  Used as a solvent and emulsifier; making epoxy resins, chlorinated compounds; and rubber.

• 発がん性

  In a 2-year inhalation carcinogenicity study in Osborne Mendel rats and B6C3F1 mice (50 of each sex at each exposure level), animals were exposed to concentrations of 0, 5, or 10 ppm AGE, 6 h/day, 5 days/ week. Although occasional respiratory epithelial tumors were observed, the NTP concluded the data provided only equivocal evidence of carcinogenicity in male rats and female mice. No evidence was obtained to support a carcinogenic effect in female rats. Some evidence was provided for a carcinogenic response in male mice, which included three adenomas of the respiratory epithelium, dysplasia in four mice, and focal basal cell hyperplasia of the respiratory epithelium in the nasal passages of seven mice .

• 環境運命予測

  Biological. Bridié et al. (1979) reported BOD and COD values of 0.06 and 1.99 g/g using filtered effluent from a biological sanitary waste treatment plant. These values were determined using a standard dilution method at 20 °C for a period of 5 d. The ThOD for allyl glycidyl ether is 2.11 g/g.
  Chemical/Physical. Hydrolysis of the epoxide ring is likely forming 1-allyloxy-2,3- dihydroxypropane (Perez and Osterman-Golkar, 2000).

• 貯蔵

  Allyl glycidyl ether should be kept stored in a cool, dark, fi reproof area separated from strong oxidants, strong bases, and strong acids.

• 輸送方法

  UN2219 Allyl glycidal ether, Hazard Class: 3; Labels: 3-Flammable liquid

• 不和合性

  May form explosive mixture with air. Contact with acids or bases may cause explosive polymerization. Contact with oxidizers or amines may cause fire and explosions.

• 廃棄物の処理

  Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

• 予防処置

  During use and/or handling of allyl glycidyl ether, occupational workers should not be near open flames, sparks, or smoking areas. For temperatures above 48°C, use a closedsystem ventilation and explosion-proof electrical equipment. Workers should use protective gloves, protective clothing, and avoid all contact.

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アリルグリシジルエーテル スペクトルデータ(¹HNMR、¹³CNMR、IR1、IR2、MS、Raman)

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