フェニルカルバミン酸イソプロピル

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H302：飲み込むと有害

フェニルカルバミン酸イソプロピル 価格

MSDS Information

• Isopropyl phenylcarbamate

フェニルカルバミン酸イソプロピル 化学特性,用途語,生産方法

• 外観

  白色, 結晶性粉末〜粉末

• 溶解性

  エタノール及びアセトンに溶け、水にほとんど溶けない。

• 農薬用途

  除草剤

• 化学的特性

  Propham is a colorless crystalline solid.

• 使用

  Herbicide, applied as a spray to the soil.

• 一般的な説明

  Colorless crystalline solid.

• 反応プロフィール

  Propham is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

• 危険性

  Toxic by ingestion.

• 健康ハザード

  Moderately toxic herbicide; exhibited low tomoderate toxicity in experimental animalswhen administered by oral, intraperitoneal,intravenous, and subcutaneous routes; skinabsorption is slow; cholinesterase inhibitor;in human ingestion can cause carbamatepoisoning, which can be lethal when takenin large amount; probable lethal oral dosein adult human estimated to be larger thanother carbamate insecticides within the range35–50 g.

• 安全性プロファイル

  Poison by intraperitoneal route. Moderately toxic to humans by ingestion. Moderately toxic experimentally by ingestion and possibly other routes. An experimental teratogen. Human mutation data reported. Questionable carcinogen with experimental neoplastigenic data. An herbicide. When heated to decomposition it emits toxic fumes of NO,. See also CARBAMATES.

• 職業ばく露

  A potential danger to those involved in the manufacture, formulation and application of this car- bamate/organonitrogen grass-control herbicide.

• 環境運命予測

  Biological. Rajagopal et al. (1989) reported that Achromobacter sp. and an Arthrobacter sp. utilized propham as a sole carbon source. Metabolites identified were Nphenylcarbamic acid, aniline, catechol, monoisopropyl carbonate, 2-propanol and carbon dioxide (Rajagopal et al., 1989).
  Soil. Readily degraded by soil microorganisms forming aniline and carbon dioxide (Humburg et al., 1989). The reported half-life in soil is approximately 15 and 5 days at 16 and 29°C, respectively (Hartley and Kidd, 1987).
  Groundwater. According to the U.S. EPA (1986) propham has a high potential to leach to groundwater.
  Plant. The major plant metabolite which was identified from soybean plants is isopropyl N-2-hydroxycarbanilate (Hartley and Kidd, 1987; Humburg et al., 1989).
  Chemical/Physical. Hydrolysis of propham yields N-phenylcarbamic acid and 2-propanol. The acid is very unstable and is spontaneously decomposed to form aniline and carbon dioxide (Still and Herrett, 1976). Emits toxic fumes of nitrogen oxides when heated to decomposition (Sax and Lewis, 1987).

• 輸送方法

  UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz- ardous material, Technical Name Required. UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

• 不和合性

  Carbamates are incompatible with reduc- ing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas. May react violently with bromine, ketones. Incompatible with azo dyes, caustics, ammonia, amines, boranes, hydrazines, strong

• 廃棄物の処理

  Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recom- mendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following pack- age label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

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