リシノール酸

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H315：皮膚刺激

  H317：アレルギー性皮膚反応を起こすおそれ

  H319：強い眼刺激

• 注意書き

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P264：取扱い後は皮膚をよく洗うこと。

  P264：取扱い後は手や顔をよく洗うこと。

  P272：汚染された作業衣は作業場から出さないこと。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P302+P352：皮膚に付着した場合：多量の水と石鹸で洗うこと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P333+P313：皮膚刺激または発疹が生じた場合：医師の診断/手当てを 受けること。

  P337+P313：眼の刺激が続く場合：医師の診断/手当てを受けること。

  P501：内容物/容器を．．．に廃棄すること。

リシノール酸 価格

リシノール酸 化学特性,用途語,生産方法

• 外観

  ごくうすい黄色〜黄褐色, 澄明〜混濁の液体

• 溶解性

  エタノール、アセトン、エーテル、クロロホルムに可溶。エタノール及びアセトンに溶け、水にほとんど溶けない。

• 解説

  リシノール酸，結晶状の塊．融点5.5 ℃，沸点245 ℃(1.33 kPa)．d₄^27.4"0.940．[α]_D²²"＋7.15°(アセトン)．n_D²⁰"1.4716．アルコール類，アセトン，エーテル，クロロホルムに可溶．ドライクリーニング用せっけんの原料．

  森北出版「化学辞典（第2版）
  

• 用途

  繊維油剤の原料。ドライクリーニング用石けんの原料。

• 説明

  Ricinoleic acid is an unsaturated omega-9 fatty acid and is an important component of the seed oil obtained from mature castor plants seeds. The compound is produced for industries by fractional distillation or saponification of hydrolysed castor oil. It is normally used in manufacturing personal care products such as deodorants. Much of ricinoleic acid characteristics and effects can be associated with castor oil.

• 化学的特性

  Ricinoleic acid (synonym castor oil fatty acid) is an unsaturated fatty acid prepared from castor oil. When Ricinoleic acid is pyrolyzed (heated in the absence of air), it breaks down in undecylenic acid and n-heptaldehyde.
  appearance yellowish, clear, viscous liquid
  specific gravity (at 25°C) 0.938 - 0.944
  refractive index (at 25°C) 1.4695 - 1.4700
  acid value mg KOH/g min.175
  iodine value 82 - 90
  saponification value mg KOH/g 180 - 190
  hydroxyl value 150 - 160
  unsaponifiable matter max. 1
  colour Gardner max. 7

• 使用

  1. soaps: Ricinoleic acid can be reacted with various bases (caustic, ammonia, ethanolamines, etc.) to produce soaps having the desired characteristics (solubility, physical characteristics, polarity, etc.) depending on the final application. Some of them are: cutting oils, industrial lubricants, emulsifiers and metal working fluids. Transparent bar soaps & high solids liquids soaps are made possible by using Ricinoleic acid. The same for industrial germicides, disinfectants and heavy duty detergents (solubilization of phenolic and cresylic bodies).
  2. surface coating: it is used as an efficient pigment/dye dispersants in inks, coatings, plastics, cosmetics, etc.
  3. textiles: Ricinoleic acid provides polarity, surface wetting and lubricity.
  4. rubber: the sodium/potassium soaps of Ricinoleic acid are emulsifiers and foam stabilizers.
  5. vinyl polymers: it's sodium soap is useful as emulsifier, stabilizer and defoamer for emulsion polymerization of resins such as PVC & PVAc
  6. food additives: it's used in the production of PGPR (polyglycerol polyricinoleate) for use in chocolate.

• 定義

  ChEBI: Ricinoleic acid is a (9Z)-12-hydroxyoctadec-9-enoic acid in which the 12-hydroxy group has R-configuration. It is a conjugate acid of a ricinoleate. It is a C18 unsaturated fatty acid that comprises 80% of the fatty acid content of castor oil.

• 発がん性

  Four rabbits given intermittent subcutaneous injections of 3120 mg/kg ricinoleic acid for 52 weeks developed subcutaneous neoplasms. The tumorigenic potential of ricinoleic acid injected intravaginally in groups of 20 mice was also studied. No tumors attributable to ricinoleic acid treatment were observed in three studies after 18–20 months.

• 純化方法

  Purify it as the methyl acetylricinoleate [Rider J Am Chem Soc 53 4130 1931], fractionally distilling it at 180-185o/0.3mm, then 87g of this ester is hydrolysed by refluxing with KOH (56g), water (25mL), and MeOH (250mL) for 10minutes. The free acid is separated on acidification and extracted into Et2O, dried (Na2SO4), filtered, evaporated and the residue is crystallised from acetone at -50o, and distilled in small batches, b 180o/0.005mm. The R-enantiomer has m +5.5o, b 245o/10mm and [] 26D +7.2o (c 5, Me2CO). [Bailey et al. J Chem Soc 3027 1957, Beilstein 3 IV 1026, 1207.]

• 参考文献

  1)　A.G. Goldsobel, Chem.Ber., 27, 3121 (1894), DOI: 10.1002/cber.18940270393.

リシノール酸 上流と下流の製品情報

リシノール酸 生産企業

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リシノール酸 スペクトルデータ(¹HNMR、¹³CNMR、IR1、MS)

141-22-0, リシノール酸 キーワード