1-アセチルアスピドスペルミジン-3α,17-ジオール

1-アセチルアスピドスペルミジン-3α,17-ジオール 化学特性,用途語,生産方法

• 説明

  A further alkaloid which has been isolated from the bark of Aspidosperma chakense Spagazzini, this base forms colourless, irregular crystals from aqueous MeOH and has [α]_D + 175.6° (CHC13). The ultraviolet spectrum in MeOH shows an absorption maximum at 258 mil with a shoulder at 285 mil. One phenolic and one non-phenolic hydroxyl groups are present and the alkaloid furnishes a crystalline hydrochloride which decomposes at 278-298°C. The oxalate crystal_x0002_lizes from Et20-MeOH with m.p. 2l2-4°C (dec.).

• 参考文献

  Djerassi et a!., Experientia, 18, 113 (1962)
  Djerassi et al., 1. Amer. Chem. Soc., 84, 3480 (1962)