ジメチルジチオカルバミン酸亜鉛

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Danger

• 危険有害性情報

  H302：飲み込むと有害

  H317：アレルギー性皮膚反応を起こすおそれ

  H318：重篤な眼の損傷

  H330：吸入すると生命に危険

  H335：呼吸器への刺激のおそれ

  H373：長期にわたる、または反復暴露により臓器の障 害のおそれ

  H410：長期的影響により水生生物に非常に強い毒性

• 注意書き

  P273：環境への放出を避けること。

  P280：保護手袋/保護衣/保護眼鏡/保護面を着用するこ と。

  P301+P312：飲み込んだ場合：気分が悪い時は医師に連絡する こと。

  P305+P351+P338：眼に入った場合：水で数分間注意深く洗うこと。次にコ ンタクトレンズを着用していて容易に外せる場合は外す こと。その後も洗浄を続けること。

  P314：気分が悪い時は、医師の診断/手当てを受けること。

ジメチルジチオカルバミン酸亜鉛 価格

MSDS Information

• Zinc bis dimethyldithiocarbamate

ジメチルジチオカルバミン酸亜鉛 化学特性,用途語,生産方法

• 外観

  白色～ほとんど白色粉末～結晶

• 解説

  ジメチルジチオカルバミン酸亜鉛 C6H12N2S4Zn の一般名。 (保護) 殺菌剤。ジメチルジチオカルバメートに塩化亜鉛を作用させて得られる有機硫黄剤で，りんごの黒点病，たばこの赤星病，その他野菜のべと病などに使用される。一般には同じ有機硫黄系の殺菌剤チウラムとの混合剤として市販されている。
  

• 化学的特性

  White and odorless when pure. Almost insoluble inwater; soluble in acetone, carbon disulfide, chloroform, dilute alkalies, and concentrated hydrochloric acid.

• 使用

  Zinc Dimethyldithiocarbamate is a member of a class of dithiocarbamates, and has been used in agriculture as a fungicide and in the rubber industry as a vulcanization accelerator.

• 定義

  ChEBI: A dithiocarbamate salt that is the zinc salt of dimethyldithiocarbamic acid. It is a broad-spectrum fungicide and bird and animal repellent that is also used to accelerate the vulcanisation of rubber.

• 空気と水の反応

  Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Insoluble in water.

• 反応プロフィール

  Zinc bis dimethyldithiocarbamate is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. Zinc bis dimethyldithiocarbamate is corrosive to iron and copper. Zinc bis dimethyldithiocarbamate is incompatible with strong oxidizing agents and acids. Zinc bis dimethyldithiocarbamate is also incompatible with mercury.

• 危険性

  Strong irritant to eyes and mucous membranes.

• 火災危険

  Zinc bis dimethyldithiocarbamate is combustible. Zinc bis dimethyldithiocarbamate may form explosive dust-air mixtures.

• 农业用途

  Fungicide, Microbiocide, Animal repellant: Ziram is an agricultural fungicide registered to control fungal diseases on a wide range of crops including stone fruits, pome fruits, nut crops, vegetables and commercially grown ornamentals, and as a soil and seed treatment. In addition, it is formulated as a bird and rabbit repellent for outdoor foliar applications to ornamentals. Registered for use in EU countries . Registered for use in the U.S.

• 製品名

  AAPROTECT®; AAVOLEX®; AAZIRA®; ACCELERATOR®-L; ACCELERATOR® MZ® Powder; ACETO ZDED®; ACETO ZDMD®; ALCOBAM ZM®; ANCANZATE ME®; CARBAZINC®; CIRAM®; CORONA COROZATE®; COROZATE®; CUMAN®; CUMAN L®; CYMATE®; DRUPINA® 90; EPTAC-1®; FUCLASIN®; FUCLASIN® ULTRA; FUKLASIN®; FUNGOSTOP®; HERMAT ZDM®; HEXAZIR®; KARBAM WHITE®; KYPZIN®; METHASAN®; METHAZATE®; MEXENE®; MEZENE®; MILBAM®; MILBAN®; MOLURAME®; MYCRONIL®; OCTOCURE ZDM-50®; ORCHARD® BRAND ZIRAM; PERKACIT ZDMC®; POMARSOL® Z FORTE; PRODARAM®; PROKIL® Ziram; RHODIACID®; SOXINAL®-PZ; SOXINOL®-PZ; TRICARBAMIX Z®; TSIMAT®; TSIRAM® (Russian); ULTRA ZINC DMC®; VANCIDE® MZ-96; VANCIDE® 51Z Dispersion (with Zinc 2-mercaptobenzothiazolate); VANCIDE® 51Z Dispersion (with Ziram); ZERLATE®; ZINCMATE®; ZIMATE®; ZIMATE®; METHYL®; ZIRAMVIS®; ZIRASAN®; ZIRBERK®; ZIREX 90®; ZIRIDE®; ZIRTHANE®; ZITOX®

• 接触アレルゲン

  Ziram is a rubber vulcanization accelerator of the dithiocarbamate group. Sensitization was reported in several patients. Ziram is also used as a fungicide and can cause contact dermatitis in agricultural workers.

• 安全性プロファイル

  Poison by ingestion,intraperitoneal, and intravenous routes. Moderately toxicby inhalation. Questionable carcinogen with experimentalcarcinogenic and tumorigenic data. An experimentalteratogen. Other experimental reproductive effects.Human mutation d

• 代謝経路

  Ziram is one of the metal containing dithiocarbamates which generates dimethyldithiocarbamic acid by being cleaved in acidic conditions and in biological media. The resulting acid is conjugated with glucose and alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic acid is further degraded to dimethylamine and CS2. An extensive review of the properties of dithiocarbamate pesticides was published by the World Health Organisation (WHO, 1988) from which much of the following information is taken.

• 純化方法

  Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. [Beilstein 4 III 149, 4 IV 234.]

ジメチルジチオカルバミン酸亜鉛 上流と下流の製品情報

ジメチルジチオカルバミン酸亜鉛 生産企業

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ジメチルジチオカルバミン酸亜鉛 スペクトルデータ(¹HNMR、IR1、IR2、Raman)

137-30-4, ジメチルジチオカルバミン酸亜鉛 キーワード