1,4-ビス(2,2,2-トリクロロ-1-ホルミルアミノエチル)ピペラジン

危険有害性情報のコード(GHS)

• 絵表示(GHS)

  

• 注意喚起語

  Warning

• 危険有害性情報

  H332：吸入すると有害

• 注意書き

  P261：粉じん/煙/ガス/ミスト/蒸気/スプレーの吸入を避ける こと。

  P271：屋外または換気の良い場所でのみ使用すること。

1,4-ビス(2,2,2-トリクロロ-1-ホルミルアミノエチル)ピペラジン 価格

1,4-ビス(2,2,2-トリクロロ-1-ホルミルアミノエチル)ピペラジン 化学特性,用途語,生産方法

• 外観

  白色,結晶性粉末～粉末

• 溶解性

  水9mg/l(20℃)。ジメチルホルムアミド,DMSO, N-メチルピロリドンに容易に溶ける。テトラヒドロフランに溶ける。アセトン,ジクロロメタン, メタノール, ジオキサン, シクロヘキサノンにわずかに溶ける。ベンゼン,石油エーテル, シクロヘキサンに溶けない。アセトンに溶け、水にほとんど溶けない。

• 用途

  DMI剤

• 説明

  Triforine is a clear light yellow colour with an ethanol (alcohol) odour and a highly flammable liquid. It is used as a fungicide for the control of black spot, powdery mildew, and diseases of rust in roses, fruits, vegetables, cereals, and ornamentals. Application of triforine acts both as a preventative and a curative fungicide and is known to destroying diseases already in the plant and also preventing disease infestations. It is also used as a post-harvest control of brown rot on peaches, nectarines, apricots, cherries, and plums.

• 使用

  Triforine is used to control powdery mildews on cereals, fruits, vines, hops, ornamentals, cucurbits and some vegetables, rusts on cereals, fruit, ornamentals and beans. It also controls Munilia spp. on stone fruit, Ascochyta blight on chrysanthemums, black spot on roses, scab on apples and fairy rings on turf. Triforine also suppresses tetranychid mite activity.

• 定義

  ChEBI: A member of the class of N-alkylpiperazines in which the two amino groups of piperazine are replaced by 1-formamido-2,2,2-trichloroethyl groups. A fungicide active against a range of diseases including powdery mildew, scab and rust.

• 一般的な説明

  Colorless crystals. Non corrosive. Used as a fungicide.

• 反応プロフィール

  A piperazine, trichloromethylformamide derivative. Decomposed in strong acid to trichloroacetaldehyde and piperazine salts, and in strongly alkaline media to chloroform and piperazine.

• 危険性

  Low toxicity by ingestion, inhalation, and skin contact. Human systemic effects.

• 作用机制

  Δ14-レダクターゼおよびΔ8→Δ7イソメラーゼを阻害し防除活性を発揮する

• 农业用途

  Fungicide: Triforine is a systemic fungicide with protectant, eridicant, and curative activity. It is locally systemic, is quickly absorbed by the plant and should be applied on or before an infection occurs. Triforine is used for control of black spot, brown rot, scab, petal blight, rust and other diseases on fruits such as apples, peaches, plumbs, nectarines, apricots, and strawberry; in hops, vegetables, cereals, and ornamentals such as roses and chrysanthemums. Triforine breaks down rapidly in the environment. Not approved for use in EU countries . Registered for use in the U.S.

• 製品名

  CELA50®; CW524®; DENARIN® FUNGINEX®; SAPROL®; TRIFORIN®; W524®

• 接触アレルゲン

  This pesticide is widely used in flower growing. Cross- reactions are expected to dichlorvos.

• 安全性プロファイル

  Low toxicity by ingestion, inhalation, and skin contact. Human systemic effects: change in taste function. When heated to decomposition emits toxic fumes of NOx and Cl-.

• 代謝経路

  Thermal reaction of triforine with several alcohols in a closed glass tube gives N-(1-alkoxy-2,2,2- trichloroethyl) formamides.

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1,4-ビス(2,2,2-トリクロロ-1-ホルミルアミノエチル)ピペラジン 生産企業

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