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Methylmagnesium chloride

Methylmagnesium chloride Structure
Methylmagnesium chloride
  • CAS No.676-58-4
  • Chemical Name:Methylmagnesium chloride
  • CBNumber:CB9774414
  • Molecular Formula:CH3ClMg
  • Formula Weight:74.79
  • MOL File:676-58-4.mol
Methylmagnesium chloride Property
  • Boiling point 66 °C
  • Density 1.013 g/mL at 25 °C
  • vapor pressure 200 hPa ( 20 °C)
  • Flash point −1 °F
  • storage temp. Store below +30°C.
  • solubility Miscible with diethyl ether and tetrahydrofuran.
  • form Liquid
  • color Pale brown to dark green
  • PH >7 (20°C in H2O)
  • explosive limit 1.5% (v/v) THF)
  • Water Solubility reacts
  • Sensitive Air & Moisture Sensitive
  • BRN 3587199
  • Exposure limits ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
    OSHA: TWA 200 ppm(590 mg/m3)
    NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
  • CAS DataBase Reference 676-58-4(CAS DataBase Reference)
  • FDA UNII M5E1132G4W
  • EPA Substance Registry System Magnesium, chloromethyl- (676-58-4)
  • UNSPSC Code 12352103
  • NACRES NA.22
Safety
Hazard and Precautionary Statements (GHS)
  • Symbol(GHS)
  • Signal wordDanger
  • Hazard statements H261-H318-H225-H260-H302-H314-H335-H351
  • Precautionary statements P305+P351+P338-P309-P310-P210-P231+P232-P280-P370+P378-P402+P404-P403+P235-P231+232
Methylmagnesium chloride Price More Price(10)
  • Brand: Sigma-Aldrich
  • Product number: 189901
  • Product name : Methylmagnesium chloride solution
  • Purity: 3.0?M in THF
  • Packaging: 100ML
  • Price: ₹6992.95
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 189901
  • Product name : Methylmagnesium chloride solution
  • Purity: 3.0?M in THF
  • Packaging: 100ML
  • Price: ₹6992.95
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 189901
  • Product name : Methylmagnesium chloride solution
  • Purity: 3.0?M in THF
  • Packaging: 4X25ML
  • Price: ₹11214.7
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich(India)
  • Product number: 189901
  • Product name : Methylmagnesium chloride solution
  • Purity: 3.0?M in THF
  • Packaging: 4X25ML
  • Price: ₹11214.7
  • Updated: 2022/06/14
  • Buy: Buy
  • Brand: Sigma-Aldrich
  • Product number: 189901
  • Product name : Methylmagnesium chloride solution
  • Purity: 3.0?M in THF
  • Packaging: 800ML
  • Price: ₹29086.78
  • Updated: 2022/06/14
  • Buy: Buy

Methylmagnesium chloride Chemical Properties,Usage,Production

  • Chemical Properties dark brown solution
  • Uses Methylmagnesium chloride is used as a Grignard reagent and an alkylating agent in organic synthesis.
  • Definition ChEBI: Methylmagnesium chloride is an alkylmagnesium halide and a one-carbon compound. available as a solutionin tetrahydrofuran.
  • Application Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.
  • Preparation reaction of methyl chloride and magnesium in anhydrous diethyl ether, usually in the presence of an initiator.
  • Reactions Methylmagnesium chloride can react with acidic hydrogen on oxygen, sulfur and alkyne carbon of compounds containing active hydrogen (such as water, alcohol, mercaptan, amine, amide, acid, sulfonic acid, etc.); Propyl bromide, etc.) undergoes a coupling reaction; it can react with oxygen and carbon dioxide, aldehydes, ketones, etc.
  • Hazard Flammable, dangerous fire and explosionrisk.
  • reaction suitability reaction type: Grignard Reaction
Methylmagnesium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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Methylmagnesium chloride Spectrum
676-58-4, Methylmagnesium chloride Related Search:
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  • CH3MgCl
  • CH3ClMg
  • 676-85-4
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