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FEMA 2129
FEMA 2129
- CAS No.1319-88-6
- Chemical Name:FEMA 2129
- CBNumber:CB9744329
- Molecular Formula:C10H12O3
- Formula Weight:180.2
- MOL File:1319-88-6.mol
FEMA 2129 Property
- Boiling point 152-154 °C(Press: 12 Torr)
- Density 1.2115 g/cm3(Temp: 25 °C)
- FEMA 2129 | BENZALDEHYDE GLYCERYL ACETAL
- color A colourless viscous liquid.
- Odor at 100.00 %. cherry bitter almond sweet
- Odor Type fruity
- JECFA Number 838
- LogP 1.98
- Substances Added to Food (formerly EAFUS) BENZALDEHYDE GLYCERYL ACETAL
- FDA UNII DTD5NUE52Q
- EPA Substance Registry System Benzaldehyde, cyclic acetal with 1,2,3-propanetriol (1319-88-6)
Safety
- Toxicity :The acute oral LD50 value in rats was reported as 3?5 ml/kg (2.42-4.09 ml/kg) and the acute dermal LD50 value in rabbits as 5 ml/kg
-
Symbol(GHS)
- Signal wordWarning
- Hazard statements H302
- Precautionary statements P264-P270-P301+P312-P330-P501
FEMA 2129 Chemical Properties,Usage,Production
-
Aroma
Used in flavor compositions where lower
volatility and improved stability towards air
(oxygen) is desirable, and Benzaldehyde as
such seems too volatile and unstable.
Benzaldehyde glycrol acetal will liberate Benzaldehyde under influence of heat, water or mild acid, conditions which frequently exist in functional products containing artificial flavor.
Benzaldehyde glycrol acetal itself has a very faint odor, barely reminiscent of Bitter Almond. Soluble in alcohol and oils.
Used in fruit flavors, imitation Almond, Cherry, Nut, etc. in concentrations equal to 100 ppm in the finished consumer product.
Chewing gum may contain up to 800 ppm of the acetal. Chewing gum is the most common outlet for this acetal. - Occurrence Has apparently not been reported to occur in nature
- Preparation The α, α?- and α, β-isomers are obtained in mixture by heating glycerol and benzaldehyde to 145 to 170°C under a stream of CO2; the isomers are subsequently isolated, exploiting the solubility differences; the α, α?-isomer is readily converted to the α, β-form by heating in the presence of HCl.
- Production Methods Benzaldehyde glycrol acetal can be produced from Benzaldehyde and Glycerin by condensation, using Phosphoric acid as a catalyst, and making use of azeotropic distillation to remove reaction water. Also by heating Glycerol and Benzaldehyde in CO2 atmosphere to 150°C. The 1,3-isomer is crystallizable and may be separated.
FEMA 2129 Preparation Products And Raw materials
Raw materials
Preparation Products
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1319-88-6, FEMA 2129Related Search:
- Ketoconazole FEMA 2129 (+)-2,3-O-BENZYLIDENE-D-THREITOL cis-[2-(2,4-Dichlorophenyl)-2-(1H-imidazol-1-ylmethyl)-1,3-dioxolan-4-yl]methyl-4-methylbenzenesulphonate 1,3-Dioxolane-4-methanol (-)-DIMETHYL 2,3-O-BENZYLIDENE-L-TARTRATE (+)-4,5-BIS[HYDROXY(DIPHENYL)METHYL]-2-METHYL-2-PHENYL-1,3-DIOXOLANE THYMELEATOXIN MEZEREIN (2R,3R)-2,3-O-(1-PHENYLETHYLIDENE)-L-TARTARIC ACID DIMETHYL ESTER Methyl 2,3:4,6-Di-O-benzylidene-α-D-mannopryanoside 2-(2,4-DICHLOROPHENYL)-2-(1H-IMIDAZOL-1-YL METHYL)-1,3-DIOXOLANE-4-METHANOL 2-(2,4-DICHLOROPHENYL)-2-(1,2,4-TRIAZOL-1-YL METHYL)-1,3-DIOXALANE-4-YL METHYL METHANE SULFONATE (-)-2,3-O-BENZYLIDENE-L-THREITOL Doconazole BENZYLIDENE CBZ-NEURAMINIC ACID 2-METHYL-2-PHENYL-4-[(PROP-2-YNYLOXY)METHYL]-1,3-DIOXOLANE 2-PHENYL-4-[(PROP-2-YNYLOXY)METHYL]-1,3-DIOXOLANE
- 香精香料中间体
- 其它原料及中间体
- 化工原料
- UNII:4JD6JK979Y
- 苯甲醛丙三醇缩醛
- 1319-88-6
- BGA*
- Benzaldehyde glycerol cyclic acetal
- 2-PHENYL-1,3-DIOXOLANE-4-METHANOL
- Benzaldehyde glycrol acetal
- Benzalglycerin
- 5-Hydroxy-2-phenyl-1,3-dioxan
- Benzyl glyceryl acetal
- FEMA 2129
- BENZALDEHYDE GLYCERYL ACETAL
- BENZAL GLYCERYL ACETAL
- Benzaldehyde,cyclicacetalwith1,2,3-propanetriol